Engineered Complex Emulsion System:  Toward Modulating the Pore Length and Morphological Architecture of Mesoporous Silicas

Engineered Complex Emulsion System:  Toward Modulating the Pore Length and Morphological Architecture of Mesoporous Silicas

In the complex alkane/P123/TEOS/H2O emulsion system, an emulsion engineering method to modulate pore length and morphological architecture of mesoporous materials has been built. With fine tuning of the synthetic parameters (e.g., the composition of the synthetic mixtures, temperature, stirring, etc...

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Veröffentlicht in:The journal of physical chemistry. B 2006-12, Vol.110 (51), p.25908-25915
Hauptverfasser: Zhang, He, Sun, Junming, Ma, Ding, Weinberg, Gisela, Su, Dang Sheng, Bao, Xinhe
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container_end_page 25915
container_issue 51
container_start_page 25908
container_title The journal of physical chemistry. B
container_volume 110
creator Zhang, He
Sun, Junming
Ma, Ding
Weinberg, Gisela
Su, Dang Sheng
Bao, Xinhe
description In the complex alkane/P123/TEOS/H2O emulsion system, an emulsion engineering method to modulate pore length and morphological architecture of mesoporous materials has been built. With fine tuning of the synthetic parameters (e.g., the composition of the synthetic mixtures, temperature, stirring, etc.), a series of chemically significant mesostructures (i.e., short-pore SBA-15 materials) with tunable pore length and morphological architecture have been successfully constructed. The effects of alkane solubilizates on pore length and particle morphology are discussed. The resulting short-pore materials would have potential applications in the fields of adsorption/separation of biomolecules and inclusion chemistry of guest species, etc.
doi_str_mv 10.1021/jp065760w
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title Engineered Complex Emulsion System:  Toward Modulating the Pore Length and Morphological Architecture of Mesoporous Silicas
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