Orientational Order in Block Copolymer Films Zone Annealed below the Order−Disorder Transition Temperature
We report measurements of rapid ordering and preferential alignment in block copolymer films zone annealed below the order−disorder transition temperature. The orientational correlation lengths measured after approximately 5 h above the glass-transition temperature (≈ 2 μm) were an order of magnitud...
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| Veröffentlicht in: | Nano letters 2007-09, Vol.7 (9), p.2789-2794 |
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| container_end_page | 2794 |
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| container_issue | 9 |
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| container_title | Nano letters |
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| creator | Berry, Brian C Bosse, August W Douglas, Jack F Jones, Ronald L Karim, Alamgir |
| description | We report measurements of rapid ordering and preferential alignment in block copolymer films zone annealed below the order−disorder transition temperature. The orientational correlation lengths measured after approximately 5 h above the glass-transition temperature (≈ 2 μm) were an order of magnitude greater than that obtained under equivalent static annealing. The ability to rapidly process polymers with inaccessible order−disorder transition temperatures suggests zone annealing as a route toward more robust nanomanufacturing methods based on block copolymer self-assembly. |
| doi_str_mv | 10.1021/nl071354s |
| format | Article |
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The orientational correlation lengths measured after approximately 5 h above the glass-transition temperature (≈ 2 μm) were an order of magnitude greater than that obtained under equivalent static annealing. The ability to rapidly process polymers with inaccessible order−disorder transition temperatures suggests zone annealing as a route toward more robust nanomanufacturing methods based on block copolymer self-assembly.</description><identifier>ISSN: 1530-6984</identifier><identifier>EISSN: 1530-6992</identifier><identifier>DOI: 10.1021/nl071354s</identifier><identifier>PMID: 17691851</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Anisotropy ; Cross-disciplinary physics: materials science; rheology ; Crystallization - methods ; Exact sciences and technology ; Macromolecular Substances - chemistry ; Materials science ; Materials Testing ; Membranes, Artificial ; Methods of nanofabrication ; Molecular Conformation ; Nanostructures - chemistry ; Nanostructures - ultrastructure ; Nanotechnology - methods ; Particle Size ; Phase Transition ; Physics ; Polymethyl Methacrylate - chemistry ; Polystyrenes - chemistry ; Self-assembly ; Surface Properties ; Temperature</subject><ispartof>Nano letters, 2007-09, Vol.7 (9), p.2789-2794</ispartof><rights>Copyright © 2007 American Chemical Society</rights><rights>2007 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a409t-8e0774821a4360573782316ff0eabc5bf5d37e5d27f125e6b6669982a65d9d8e3</citedby><cites>FETCH-LOGICAL-a409t-8e0774821a4360573782316ff0eabc5bf5d37e5d27f125e6b6669982a65d9d8e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/nl071354s$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/nl071354s$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2763,27074,27922,27923,56736,56786</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=19070044$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17691851$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Berry, Brian C</creatorcontrib><creatorcontrib>Bosse, August W</creatorcontrib><creatorcontrib>Douglas, Jack F</creatorcontrib><creatorcontrib>Jones, Ronald L</creatorcontrib><creatorcontrib>Karim, Alamgir</creatorcontrib><title>Orientational Order in Block Copolymer Films Zone Annealed below the Order−Disorder Transition Temperature</title><title>Nano letters</title><addtitle>Nano Lett</addtitle><description>We report measurements of rapid ordering and preferential alignment in block copolymer films zone annealed below the order−disorder transition temperature. The orientational correlation lengths measured after approximately 5 h above the glass-transition temperature (≈ 2 μm) were an order of magnitude greater than that obtained under equivalent static annealing. The ability to rapidly process polymers with inaccessible order−disorder transition temperatures suggests zone annealing as a route toward more robust nanomanufacturing methods based on block copolymer self-assembly.</description><subject>Anisotropy</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Crystallization - methods</subject><subject>Exact sciences and technology</subject><subject>Macromolecular Substances - chemistry</subject><subject>Materials science</subject><subject>Materials Testing</subject><subject>Membranes, Artificial</subject><subject>Methods of nanofabrication</subject><subject>Molecular Conformation</subject><subject>Nanostructures - chemistry</subject><subject>Nanostructures - ultrastructure</subject><subject>Nanotechnology - methods</subject><subject>Particle Size</subject><subject>Phase Transition</subject><subject>Physics</subject><subject>Polymethyl Methacrylate - chemistry</subject><subject>Polystyrenes - chemistry</subject><subject>Self-assembly</subject><subject>Surface Properties</subject><subject>Temperature</subject><issn>1530-6984</issn><issn>1530-6992</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkLFOwzAQhi0EoqUw8ALIC0gMATuJ7WQshQJSpS5lYYmc5CJcHLvYiVDfgJlH5ElIadQuTHc6ffef7kPonJIbSkJ6azQRNGKxP0BDyiIS8DQND3d9Eg_QifdLQkgaMXKMBlTwlCaMDpGeOwWmkY2yRmo8dyU4rAy-07Z4xxO7snpdd6Op0rXHr9YAHhsDUkOJc9D2EzdvsF37-fq-V97-JSycNF5tQvEC6hU42bQOTtFRJbWHs76O0Mv0YTF5Cmbzx-fJeBbImKRNkAARIk5CKuOIEyYikYQR5VVFQOYFyytWRgJYGYqKhgx4znn3cBJKzsq0TCAaoatt7srZjxZ8k9XKF6C1NGBbn_Ek5Ixy1oHXW7Bw1nsHVbZyqpZunVGSbdRmO7Ude9GHtnkN5Z7sXXbAZQ9IX0hddQoK5fdcSgQhcbznZOGzpW1dJ97_c_AX7nGOOQ</recordid><startdate>20070901</startdate><enddate>20070901</enddate><creator>Berry, Brian C</creator><creator>Bosse, August W</creator><creator>Douglas, Jack F</creator><creator>Jones, Ronald L</creator><creator>Karim, Alamgir</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20070901</creationdate><title>Orientational Order in Block Copolymer Films Zone Annealed below the Order−Disorder Transition Temperature</title><author>Berry, Brian C ; Bosse, August W ; Douglas, Jack F ; Jones, Ronald L ; Karim, Alamgir</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a409t-8e0774821a4360573782316ff0eabc5bf5d37e5d27f125e6b6669982a65d9d8e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Anisotropy</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Crystallization - methods</topic><topic>Exact sciences and technology</topic><topic>Macromolecular Substances - chemistry</topic><topic>Materials science</topic><topic>Materials Testing</topic><topic>Membranes, Artificial</topic><topic>Methods of nanofabrication</topic><topic>Molecular Conformation</topic><topic>Nanostructures - chemistry</topic><topic>Nanostructures - ultrastructure</topic><topic>Nanotechnology - methods</topic><topic>Particle Size</topic><topic>Phase Transition</topic><topic>Physics</topic><topic>Polymethyl Methacrylate - chemistry</topic><topic>Polystyrenes - chemistry</topic><topic>Self-assembly</topic><topic>Surface Properties</topic><topic>Temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Berry, Brian C</creatorcontrib><creatorcontrib>Bosse, August W</creatorcontrib><creatorcontrib>Douglas, Jack F</creatorcontrib><creatorcontrib>Jones, Ronald L</creatorcontrib><creatorcontrib>Karim, Alamgir</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Nano letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Berry, Brian C</au><au>Bosse, August W</au><au>Douglas, Jack F</au><au>Jones, Ronald L</au><au>Karim, Alamgir</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Orientational Order in Block Copolymer Films Zone Annealed below the Order−Disorder Transition Temperature</atitle><jtitle>Nano letters</jtitle><addtitle>Nano Lett</addtitle><date>2007-09-01</date><risdate>2007</risdate><volume>7</volume><issue>9</issue><spage>2789</spage><epage>2794</epage><pages>2789-2794</pages><issn>1530-6984</issn><eissn>1530-6992</eissn><abstract>We report measurements of rapid ordering and preferential alignment in block copolymer films zone annealed below the order−disorder transition temperature. The orientational correlation lengths measured after approximately 5 h above the glass-transition temperature (≈ 2 μm) were an order of magnitude greater than that obtained under equivalent static annealing. The ability to rapidly process polymers with inaccessible order−disorder transition temperatures suggests zone annealing as a route toward more robust nanomanufacturing methods based on block copolymer self-assembly.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>17691851</pmid><doi>10.1021/nl071354s</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1530-6984 |
| ispartof | Nano letters, 2007-09, Vol.7 (9), p.2789-2794 |
| issn | 1530-6984 1530-6992 |
| language | eng |
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| source | MEDLINE; ACS Publications |
| subjects | Anisotropy Cross-disciplinary physics: materials science rheology Crystallization - methods Exact sciences and technology Macromolecular Substances - chemistry Materials science Materials Testing Membranes, Artificial Methods of nanofabrication Molecular Conformation Nanostructures - chemistry Nanostructures - ultrastructure Nanotechnology - methods Particle Size Phase Transition Physics Polymethyl Methacrylate - chemistry Polystyrenes - chemistry Self-assembly Surface Properties Temperature |
| title | Orientational Order in Block Copolymer Films Zone Annealed below the Order−Disorder Transition Temperature |
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