Cationic Palladium Complex Catalyzed Highly Enantioselective Intramolecular Addition of Arylboronic Acids to Ketones. A Convenient Synthesis of Optically Active Cycloalkanols

An efficient and convenient synthesis of optically active cycloalkanols by utilizing the chiral cationic palladium complex as the catalyst was achieved in mild conditions with high yield and high enantioselectivity.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of the American Chemical Society 2006-12, Vol.128 (51), p.16504-16505
Hauptverfasser:	Liu, Guixia, Lu, Xiyan
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetylation Alcohols - chemical synthesis Alcohols - chemistry Boronic Acids - chemistry Catalysis Cations - chemistry Chemistry Cyclization Exact sciences and technology General and physical chemistry Ketones - chemistry Molecular Structure Optical Rotation Organometallic Compounds - chemistry Palladium - chemistry Stereoisomerism
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Beschreibung
Zusammenfassung:	An efficient and convenient synthesis of optically active cycloalkanols by utilizing the chiral cationic palladium complex as the catalyst was achieved in mild conditions with high yield and high enantioselectivity.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja0672425