Diastereoselective Addition of Enantiopure Lithium tert-Butylsulfinylferrocene to Imines

(S)-tert-Butylsulfinylferrocene was submitted to ortho-metalation, and the corresponding lithium derivative was trapped by alkyl or aryl imines bearing various electron-withdrawing groups on the nitrogen atom (Ts, Dpp, Boc). New aminosulfoxides were obtained with complete diastereocontrol when Dpp o...

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Veröffentlicht in:	Journal of organic chemistry 2006-12, Vol.71 (26), p.9572-9579
Hauptverfasser:	Grach, Guillaume, Sopkova-de Oliveira Santos, Jana, Lohier, Jean-François, Mojovic, Ljubica, Plé, Nelly, Turck, Alain, Reboul, Vincent, Metzner, Patrick
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Crystallography, X-Ray Exact sciences and technology Ferrous Compounds - chemical synthesis Ferrous Compounds - chemistry Imines - chemistry Lithium - chemistry Models, Molecular Molecular Conformation Organic chemistry Stereoisomerism
Online-Zugang:	Volltext
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