Self-Supported Oligomeric Grubbs/Hoveyda-Type Ru−Carbene Complexes for Ring-Closing Metathesis

Self-Supported Oligomeric Grubbs/Hoveyda-Type Ru−Carbene Complexes for Ring-Closing Metathesis

On the basis of the release−return metathesis mechanism, self-supported oligomeric Grubbs/Hoveyda-type Ru−carbene complexes have been designed and synthesized as a new type of recoverable catalyst for ring-closing metathesis. The catalytic activities of the self-supported oligomeric Ru−carbene compl...

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Veröffentlicht in:Organic letters 2007-09, Vol.9 (19), p.3845-3848
Hauptverfasser: Chen, Shu-Wei, Kim, Ju Hyun, Song, Choong Eui, Lee, Sang-gi
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container_title Organic letters
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creator Chen, Shu-Wei
Kim, Ju Hyun
Song, Choong Eui
Lee, Sang-gi
description On the basis of the release−return metathesis mechanism, self-supported oligomeric Grubbs/Hoveyda-type Ru−carbene complexes have been designed and synthesized as a new type of recoverable catalyst for ring-closing metathesis. The catalytic activities of the self-supported oligomeric Ru−carbene complex in ring-closing metathesis are comparable to those of their homogeneous counterpart as they work homogeneously and are recovered heterogeneously.
doi_str_mv 10.1021/ol7016774
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title Self-Supported Oligomeric Grubbs/Hoveyda-Type Ru−Carbene Complexes for Ring-Closing Metathesis
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