Nitrosonium Complexes of Resorc[4]arenes:  Spectral, Kinetic, and Theoretical Studies

Resorc[4]arene octamethyl ethers 1−3, when treated with NOBF4 salt in chloroform, form very stable 1:1 nitrosonium (NO+) complexes, which are deeply colored. The complexation process is reversible, and the complexes dissociate and bleach upon addition of methanol or water, to give the starting macro...

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Veröffentlicht in:	Journal of the American Chemical Society 2007-09, Vol.129 (36), p.11202-11212
Hauptverfasser:	Botta, Bruno, D'Acquarica, Ilaria, Monache, Giuliano Delle, Nevola, Laura, Tullo, Danila, Ugozzoli, Franco, Pierini, Marco
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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