A New Catalytic Route for the Activation of sp-Hybridized Carbon-Hydrogen Bonds
Vinyl‐substituted silicon compounds react selectively with terminal alkynes in the presence of complexes containing [Ru]H and [Ru]Si bonds to form functionalized silylethynes (see picture). This reaction opens up a new catalytic route for the preparation of a class of potent organosilicon reagents...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2006-12, Vol.45 (48), p.8180-8184 |
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| container_end_page | 8184 |
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| container_issue | 48 |
| container_start_page | 8180 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 45 |
| creator | Marciniec, Bogdan Dudziec, Beata Kownacki, Ireneusz |
| description | Vinyl‐substituted silicon compounds react selectively with terminal alkynes in the presence of complexes containing [Ru]H and [Ru]Si bonds to form functionalized silylethynes (see picture). This reaction opens up a new catalytic route for the preparation of a class of potent organosilicon reagents for organic synthesis. |
| doi_str_mv | 10.1002/anie.200603582 |
| format | Article |
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| identifier | ISSN: 1433-7851 |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | alkynes CH activation homogeneous catalysis ruthenium silanes |
| title | A New Catalytic Route for the Activation of sp-Hybridized Carbon-Hydrogen Bonds |
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