A kinetic parameter concerning mass transfer in silica monolithic and particulate stationary phases measured by the peak-parking and slow-elution methods

Mass transfer in monolithic C18‐silica stationary phases and C18‐silica gel particles was studied. A traditional kinetic parameter, γsDs, which is a diffusion coefficient of solute molecules in the stationary phase, was measured by two unusual approaches, i. e., peak‐parking and slow‐elution methods...

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Veröffentlicht in:Journal of separation science 2006-11, Vol.29 (16), p.2452-2462
Hauptverfasser: Miyabe, Kanji, Kobayashi, Hiroshi, Tokuda, Daisuke, Tanaka, Nobuo
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Sprache:eng
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