A direct and fast method to monitor lipid oxidation progress in model fatty acid methyl esters by high-performance size-exclusion chromatography
A new method based on high-performance size-exclusion chromatography (HPSEC) is proposed to quantitate primary and secondary oxidation compounds in model fatty acid methyl esters (FAMEs). The method consists on simply injecting an aliquot sample in HPSEC, without preliminary isolation procedures nei...
Gespeichert in:
| Veröffentlicht in: | Journal of Chromatography A 2007-09, Vol.1165 (1), p.122-127 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 127 |
|---|---|
| container_issue | 1 |
| container_start_page | 122 |
| container_title | Journal of Chromatography A |
| container_volume | 1165 |
| creator | Márquez-Ruiz, G. Holgado, F. García-Martínez, M.C. Dobarganes, M.C. |
| description | A new method based on high-performance size-exclusion chromatography (HPSEC) is proposed to quantitate primary and secondary oxidation compounds in model fatty acid methyl esters (FAMEs). The method consists on simply injecting an aliquot sample in HPSEC, without preliminary isolation procedures neither addition of standard internal. Four groups of compounds can be quantified, namely, unoxidised FAME, oxidised FAME monomers including hydroperoxides, FAME dimers and FAME polymers. Results showed high repeatability and sensitivity, and substantial advantages versus determination of residual substrate by gas–liquid chromatography. Applicability of the method is shown through selected data obtained by numerous oxidation experiments on pure FAME, mainly methyl linoleate, at ambient and moderate temperatures. |
| doi_str_mv | 10.1016/j.chroma.2007.08.001 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_68227638</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0021967307013350</els_id><sourcerecordid>68227638</sourcerecordid><originalsourceid>FETCH-LOGICAL-c390t-da348cf82102353905affcc808189b56d0004b45cdc8d4fa33845388620ec9e73</originalsourceid><addsrcrecordid>eNp9kU2L1TAUhrNQnHH0H4hko7vWk6Rt0o0wDH7BgBtdh9zkdJpL29QkV6b-Cn-yufTC7FwFDs_7cs4TQt4wqBmw7sOxtmMMs6k5gKxB1QDsGbkG4KzqOymuyMuUjmUoQfIX5IpJCR0X_Jr8vaXOR7SZmsXRwaRMZ8xjcDQHOofF5xDp5FfvaHj0zmQfFrrG8BAxJeqXwjicSjDnjRpbsHN8myimjDHRw0ZH_zBWK8YhxNksFmnyf7DCRzud0rltXz2XSrOO2yvyfDBTwteX94b8_Pzpx93X6v77l293t_eVFT3kyhnRKDsozoCLtoxaMwzWKlBM9Ye2cwDQHJrWOqtcMxghVNMKpToOaHuU4oa833vLMb9OZVs9-2RxmsyC4ZR0pziXnVAFbHbQxpBSxEGv0c8mbpqBPtvXR72foM_2NShdRJfY20v_6TCjewpd1Bfg3QUwyZppiMWNT09cD0Iy3hTu485hsfHbY9TJeiwe93_TLvj_b_IPdLupqw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>68227638</pqid></control><display><type>article</type><title>A direct and fast method to monitor lipid oxidation progress in model fatty acid methyl esters by high-performance size-exclusion chromatography</title><source>MEDLINE</source><source>Elsevier ScienceDirect Journals</source><creator>Márquez-Ruiz, G. ; Holgado, F. ; García-Martínez, M.C. ; Dobarganes, M.C.</creator><creatorcontrib>Márquez-Ruiz, G. ; Holgado, F. ; García-Martínez, M.C. ; Dobarganes, M.C.</creatorcontrib><description>A new method based on high-performance size-exclusion chromatography (HPSEC) is proposed to quantitate primary and secondary oxidation compounds in model fatty acid methyl esters (FAMEs). The method consists on simply injecting an aliquot sample in HPSEC, without preliminary isolation procedures neither addition of standard internal. Four groups of compounds can be quantified, namely, unoxidised FAME, oxidised FAME monomers including hydroperoxides, FAME dimers and FAME polymers. Results showed high repeatability and sensitivity, and substantial advantages versus determination of residual substrate by gas–liquid chromatography. Applicability of the method is shown through selected data obtained by numerous oxidation experiments on pure FAME, mainly methyl linoleate, at ambient and moderate temperatures.</description><identifier>ISSN: 0021-9673</identifier><identifier>DOI: 10.1016/j.chroma.2007.08.001</identifier><identifier>PMID: 17706232</identifier><identifier>CODEN: JOCRAM</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Aliphatic compounds ; Analytical chemistry ; Chemistry ; Chromatographic methods and physical methods associated with chromatography ; Chromatography, Gel - methods ; Exact sciences and technology ; FAME ; High-performance size-exclusion chromatography ; Linoleic Acids - chemistry ; Linoleic Acids - isolation & purification ; Linolenic Acids - chemistry ; Linolenic Acids - isolation & purification ; Lipid oxidation ; Methyl linoleate ; Oleic Acids - isolation & purification ; Organic chemistry ; Other chromatographic methods ; Oxidation kinetics ; Oxidation-Reduction ; Preparations and properties ; Temperature ; Tocopherol</subject><ispartof>Journal of Chromatography A, 2007-09, Vol.1165 (1), p.122-127</ispartof><rights>2007 Elsevier B.V.</rights><rights>2007 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c390t-da348cf82102353905affcc808189b56d0004b45cdc8d4fa33845388620ec9e73</citedby><cites>FETCH-LOGICAL-c390t-da348cf82102353905affcc808189b56d0004b45cdc8d4fa33845388620ec9e73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.chroma.2007.08.001$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,777,781,3537,27905,27906,45976</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=19037124$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17706232$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Márquez-Ruiz, G.</creatorcontrib><creatorcontrib>Holgado, F.</creatorcontrib><creatorcontrib>García-Martínez, M.C.</creatorcontrib><creatorcontrib>Dobarganes, M.C.</creatorcontrib><title>A direct and fast method to monitor lipid oxidation progress in model fatty acid methyl esters by high-performance size-exclusion chromatography</title><title>Journal of Chromatography A</title><addtitle>J Chromatogr A</addtitle><description>A new method based on high-performance size-exclusion chromatography (HPSEC) is proposed to quantitate primary and secondary oxidation compounds in model fatty acid methyl esters (FAMEs). The method consists on simply injecting an aliquot sample in HPSEC, without preliminary isolation procedures neither addition of standard internal. Four groups of compounds can be quantified, namely, unoxidised FAME, oxidised FAME monomers including hydroperoxides, FAME dimers and FAME polymers. Results showed high repeatability and sensitivity, and substantial advantages versus determination of residual substrate by gas–liquid chromatography. Applicability of the method is shown through selected data obtained by numerous oxidation experiments on pure FAME, mainly methyl linoleate, at ambient and moderate temperatures.</description><subject>Aliphatic compounds</subject><subject>Analytical chemistry</subject><subject>Chemistry</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>Chromatography, Gel - methods</subject><subject>Exact sciences and technology</subject><subject>FAME</subject><subject>High-performance size-exclusion chromatography</subject><subject>Linoleic Acids - chemistry</subject><subject>Linoleic Acids - isolation & purification</subject><subject>Linolenic Acids - chemistry</subject><subject>Linolenic Acids - isolation & purification</subject><subject>Lipid oxidation</subject><subject>Methyl linoleate</subject><subject>Oleic Acids - isolation & purification</subject><subject>Organic chemistry</subject><subject>Other chromatographic methods</subject><subject>Oxidation kinetics</subject><subject>Oxidation-Reduction</subject><subject>Preparations and properties</subject><subject>Temperature</subject><subject>Tocopherol</subject><issn>0021-9673</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kU2L1TAUhrNQnHH0H4hko7vWk6Rt0o0wDH7BgBtdh9zkdJpL29QkV6b-Cn-yufTC7FwFDs_7cs4TQt4wqBmw7sOxtmMMs6k5gKxB1QDsGbkG4KzqOymuyMuUjmUoQfIX5IpJCR0X_Jr8vaXOR7SZmsXRwaRMZ8xjcDQHOofF5xDp5FfvaHj0zmQfFrrG8BAxJeqXwjicSjDnjRpbsHN8myimjDHRw0ZH_zBWK8YhxNksFmnyf7DCRzud0rltXz2XSrOO2yvyfDBTwteX94b8_Pzpx93X6v77l293t_eVFT3kyhnRKDsozoCLtoxaMwzWKlBM9Ye2cwDQHJrWOqtcMxghVNMKpToOaHuU4oa833vLMb9OZVs9-2RxmsyC4ZR0pziXnVAFbHbQxpBSxEGv0c8mbpqBPtvXR72foM_2NShdRJfY20v_6TCjewpd1Bfg3QUwyZppiMWNT09cD0Iy3hTu485hsfHbY9TJeiwe93_TLvj_b_IPdLupqw</recordid><startdate>20070921</startdate><enddate>20070921</enddate><creator>Márquez-Ruiz, G.</creator><creator>Holgado, F.</creator><creator>García-Martínez, M.C.</creator><creator>Dobarganes, M.C.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20070921</creationdate><title>A direct and fast method to monitor lipid oxidation progress in model fatty acid methyl esters by high-performance size-exclusion chromatography</title><author>Márquez-Ruiz, G. ; Holgado, F. ; García-Martínez, M.C. ; Dobarganes, M.C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c390t-da348cf82102353905affcc808189b56d0004b45cdc8d4fa33845388620ec9e73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Aliphatic compounds</topic><topic>Analytical chemistry</topic><topic>Chemistry</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>Chromatography, Gel - methods</topic><topic>Exact sciences and technology</topic><topic>FAME</topic><topic>High-performance size-exclusion chromatography</topic><topic>Linoleic Acids - chemistry</topic><topic>Linoleic Acids - isolation & purification</topic><topic>Linolenic Acids - chemistry</topic><topic>Linolenic Acids - isolation & purification</topic><topic>Lipid oxidation</topic><topic>Methyl linoleate</topic><topic>Oleic Acids - isolation & purification</topic><topic>Organic chemistry</topic><topic>Other chromatographic methods</topic><topic>Oxidation kinetics</topic><topic>Oxidation-Reduction</topic><topic>Preparations and properties</topic><topic>Temperature</topic><topic>Tocopherol</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Márquez-Ruiz, G.</creatorcontrib><creatorcontrib>Holgado, F.</creatorcontrib><creatorcontrib>García-Martínez, M.C.</creatorcontrib><creatorcontrib>Dobarganes, M.C.</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of Chromatography A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Márquez-Ruiz, G.</au><au>Holgado, F.</au><au>García-Martínez, M.C.</au><au>Dobarganes, M.C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A direct and fast method to monitor lipid oxidation progress in model fatty acid methyl esters by high-performance size-exclusion chromatography</atitle><jtitle>Journal of Chromatography A</jtitle><addtitle>J Chromatogr A</addtitle><date>2007-09-21</date><risdate>2007</risdate><volume>1165</volume><issue>1</issue><spage>122</spage><epage>127</epage><pages>122-127</pages><issn>0021-9673</issn><coden>JOCRAM</coden><abstract>A new method based on high-performance size-exclusion chromatography (HPSEC) is proposed to quantitate primary and secondary oxidation compounds in model fatty acid methyl esters (FAMEs). The method consists on simply injecting an aliquot sample in HPSEC, without preliminary isolation procedures neither addition of standard internal. Four groups of compounds can be quantified, namely, unoxidised FAME, oxidised FAME monomers including hydroperoxides, FAME dimers and FAME polymers. Results showed high repeatability and sensitivity, and substantial advantages versus determination of residual substrate by gas–liquid chromatography. Applicability of the method is shown through selected data obtained by numerous oxidation experiments on pure FAME, mainly methyl linoleate, at ambient and moderate temperatures.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>17706232</pmid><doi>10.1016/j.chroma.2007.08.001</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-9673 |
| ispartof | Journal of Chromatography A, 2007-09, Vol.1165 (1), p.122-127 |
| issn | 0021-9673 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_68227638 |
| source | MEDLINE; Elsevier ScienceDirect Journals |
| subjects | Aliphatic compounds Analytical chemistry Chemistry Chromatographic methods and physical methods associated with chromatography Chromatography, Gel - methods Exact sciences and technology FAME High-performance size-exclusion chromatography Linoleic Acids - chemistry Linoleic Acids - isolation & purification Linolenic Acids - chemistry Linolenic Acids - isolation & purification Lipid oxidation Methyl linoleate Oleic Acids - isolation & purification Organic chemistry Other chromatographic methods Oxidation kinetics Oxidation-Reduction Preparations and properties Temperature Tocopherol |
| title | A direct and fast method to monitor lipid oxidation progress in model fatty acid methyl esters by high-performance size-exclusion chromatography |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T01%3A46%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20direct%20and%20fast%20method%20to%20monitor%20lipid%20oxidation%20progress%20in%20model%20fatty%20acid%20methyl%20esters%20by%20high-performance%20size-exclusion%20chromatography&rft.jtitle=Journal%20of%20Chromatography%20A&rft.au=M%C3%A1rquez-Ruiz,%20G.&rft.date=2007-09-21&rft.volume=1165&rft.issue=1&rft.spage=122&rft.epage=127&rft.pages=122-127&rft.issn=0021-9673&rft.coden=JOCRAM&rft_id=info:doi/10.1016/j.chroma.2007.08.001&rft_dat=%3Cproquest_cross%3E68227638%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=68227638&rft_id=info:pmid/17706232&rft_els_id=S0021967307013350&rfr_iscdi=true |