Crystalline Graphite from an Organometallic Solution-Phase Reaction

Crystalline Graphite from an Organometallic Solution-Phase Reaction

We report a chemical method by which graphitic carbon is prepared at reaction temperatures as low as 110 °C from readily available molecular reagents. This process requires no forcing conditions such as high pressures, intense light, or electrical discharge but is a simple, catalytic organometallic...

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Veröffentlicht in:Journal of the American Chemical Society 2006-12, Vol.128 (49), p.15590-15591
Hauptverfasser: Walter, Erich C, Beetz, Tobias, Sfeir, Matthew Y, Brus, Louis E, Steigerwald, Michael L
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Exact sciences and technology
General and physical chemistry
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container_end_page 15591
container_issue 49
container_start_page 15590
container_title Journal of the American Chemical Society
container_volume 128
creator Walter, Erich C
Beetz, Tobias
Sfeir, Matthew Y
Brus, Louis E
Steigerwald, Michael L
description We report a chemical method by which graphitic carbon is prepared at reaction temperatures as low as 110 °C from readily available molecular reagents. This process requires no forcing conditions such as high pressures, intense light, or electrical discharge but is a simple, catalytic organometallic reaction. The carbon forms in a variety of morphologies including graphene sheets and nanotubes. The mild reaction conditions are similar to those routinely employed in homogeneous catalysis; therefore, they will allow the subtle manipulation of reaction variables to give desired morphologies selectively.
doi_str_mv 10.1021/ja0666203
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subjects Chemistry
Exact sciences and technology
General and physical chemistry
title Crystalline Graphite from an Organometallic Solution-Phase Reaction
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