Synthesis, Structural Characterization, and Theoretical Investigation of Compounds Containing an Al−O−M−O−Al (M = Ti, Zr) Core

We report a facile route to the first molecular compounds with the Al−O−M−O−Al (M = Ti, Zr) structural motif. Synthesis of L(Me)Al(μ-O)M(NMe2)2(μ-O)Al(Me)L [L = CH{N(Ar)(CMe)}2, Ar = 2,6-iPr2C6H3; M = Ti (7), Zr (8)] was accomplished by reacting the monometallic hydroxide precursor L(Me)Al(OH) (1) w...

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Veröffentlicht in:	Inorganic chemistry 2007-09, Vol.46 (18), p.7594-7600
Hauptverfasser:	Mandal, Swadhin K, Gurubasavaraj, Prabhuodeyara M, Roesky, Herbert W, Oswald, Rainer B, Magull, Jörg, Ringe, Arne
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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