Macroscopic Hierarchical Surface Patterning of Porphyrin Trimers via Self-Assembly and Dewetting
The use of bottom-up approaches to construct patterned surfaces for technological applications is appealing, but to date is applicable to only relatively small areas (~10 square micrometers). We constructed highly periodic patterns at macroscopic length scales, in the range of square millimeters, by...
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| Veröffentlicht in: | Science (American Association for the Advancement of Science) 2006-12, Vol.314 (5804), p.1433-1436 |
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| creator | Hameren, Richard Van Schön, Peter Buul, Arend M. Van Hoogboom, Johan Lazarenko, Sergiy V Gerritsen, Jan W Engelkamp, Hans Christianen, Peter C.M Heus, Hans A Maan, Jan C Rasing, Theo Speller, Sylvia Rowan, Alan E Elemans, Johannes A.A.W Nolte, Roeland J.M |
| description | The use of bottom-up approaches to construct patterned surfaces for technological applications is appealing, but to date is applicable to only relatively small areas (~10 square micrometers). We constructed highly periodic patterns at macroscopic length scales, in the range of square millimeters, by combining self-assembly of disk-like porphyrin dyes with physical dewetting phenomena. The patterns consisted of equidistant 5-nanometer-wide lines spaced 0.5 to 1 micrometers apart, forming single porphyrin stacks containing millions of molecules, and were formed spontaneously upon drop-casting a solution of the molecules onto a mica surface. On glass, thicker lines are formed, which can be used to align liquid crystals in large domains of square millimeter size. |
| doi_str_mv | 10.1126/science.1133004 |
| format | Article |
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Van ; Hoogboom, Johan ; Lazarenko, Sergiy V ; Gerritsen, Jan W ; Engelkamp, Hans ; Christianen, Peter C.M ; Heus, Hans A ; Maan, Jan C ; Rasing, Theo ; Speller, Sylvia ; Rowan, Alan E ; Elemans, Johannes A.A.W ; Nolte, Roeland J.M</creator><creatorcontrib>Hameren, Richard Van ; Schön, Peter ; Buul, Arend M. Van ; Hoogboom, Johan ; Lazarenko, Sergiy V ; Gerritsen, Jan W ; Engelkamp, Hans ; Christianen, Peter C.M ; Heus, Hans A ; Maan, Jan C ; Rasing, Theo ; Speller, Sylvia ; Rowan, Alan E ; Elemans, Johannes A.A.W ; Nolte, Roeland J.M</creatorcontrib><description>The use of bottom-up approaches to construct patterned surfaces for technological applications is appealing, but to date is applicable to only relatively small areas (~10 square micrometers). We constructed highly periodic patterns at macroscopic length scales, in the range of square millimeters, by combining self-assembly of disk-like porphyrin dyes with physical dewetting phenomena. The patterns consisted of equidistant 5-nanometer-wide lines spaced 0.5 to 1 micrometers apart, forming single porphyrin stacks containing millions of molecules, and were formed spontaneously upon drop-casting a solution of the molecules onto a mica surface. 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| ispartof | Science (American Association for the Advancement of Science), 2006-12, Vol.314 (5804), p.1433-1436 |
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| source | American Association for the Advancement of Science; Jstor Complete Legacy |
| subjects | Applied sciences Cell aggregates Columnar crystals Construction Crystals Dewetting Evaporation Exact sciences and technology Glass Liquid crystals Mica Micrometers Molecules Organic polymers Parallel lines Physicochemistry of polymers Porphyrins Properties and characterization Self assembly Solvents Structure, morphology and analysis Trimers |
| title | Macroscopic Hierarchical Surface Patterning of Porphyrin Trimers via Self-Assembly and Dewetting |
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