A Computationally Designed Rh(I)-Catalyzed Two-Component [5+2+1] Cycloaddition of Ene-vinylcyclopropanes and CO for the Synthesis of Cyclooctenones

Through the combined use of computational (density functional theory) and experimental studies, a new [Rh(CO)2Cl]2 catalyzed two-component [5+2+1] cycloaddition of ene-vinylcyclopropanes and CO for the synthesis of fused bicyclic cyclooctenones has been designed and experimentally realized. The key...

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Veröffentlicht in:	Journal of the American Chemical Society 2007-08, Vol.129 (33), p.10060-10061
Hauptverfasser:	Wang, Yuanyuan, Wang, Jingxin, Su, Jiachun, Huang, Feng, Jiao, Lei, Liang, Yong, Yang, Dazhi, Zhang, Shiwei, Wender, Paul A, Yu, Zhi-Xiang
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon Monoxide - chemistry Catalysis Cyclization Cyclooctanes - chemical synthesis Cyclopropanes - chemistry Ketones - chemical synthesis Rhodium - chemistry Vinyl Compounds - chemistry
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