A peptide co-solvent under scrutiny: self-aggregation of 2,2,2-trifluoroethanol

Trifluoroethanol (TFE) and its aggregates are studied via supersonic jet FTIR and Raman spectroscopy as well as by quantum chemistry and simple force field approaches. A multi-slit nozzle is introduced to study collisionally excited clusters. Efforts are made to extract harmonic frequencies from exp...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2007-08, Vol.9 (32), p.4472-4490
Hauptverfasser:	Scharge, Tina, Cézard, Christine, Zielke, Philipp, Schütz, Anne, Emmeluth, Corinna, Suhm, Martin A
Format:	Artikel
Sprache:	eng
Schlagworte:	Dimerization Hydrogen Bonding Peptides - chemistry Protein Conformation Quantum Theory Spectroscopy, Fourier Transform Infrared Spectrum Analysis, Raman Trifluoroethanol - chemistry
Online-Zugang:	Volltext
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