Electrophilic Ruthenium(VI) Nitrido Complex Containing Kläui's Oxygen Tripodal Ligand

Electrophilic Ruthenium(VI) Nitrido Complex Containing Kläui's Oxygen Tripodal Ligand

Treatment of [n-Bu4N][Ru(N)Cl4] with [AgLOEt] (LOEt - = [(η5-C5H5)Co{P(O)(OEt)2}3]-) afforded the ruthenium(VI) nitrido complex [LOEtRu(N)Cl2] (1), which reacted with PPh3 to give the ruthenium(IV) phosphiniminato complex [LOEtRu(NPPh3)Cl2] (2). The cyclic voltammogram of 2 displays the RuIV/III cou...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Inorganic chemistry 2007-08, Vol.46 (17), p.7193-7198
Hauptverfasser: Yi, Lam, Tony C. H, Sau, Yiu-Keung, Zhang, Qian-Feng, Williams, Ian D, Leung, Wa-Hung
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 7198
container_issue 17
container_start_page 7193
container_title Inorganic chemistry
container_volume 46
creator Yi
Lam, Tony C. H
Sau, Yiu-Keung
Zhang, Qian-Feng
Williams, Ian D
Leung, Wa-Hung
description Treatment of [n-Bu4N][Ru(N)Cl4] with [AgLOEt] (LOEt - = [(η5-C5H5)Co{P(O)(OEt)2}3]-) afforded the ruthenium(VI) nitrido complex [LOEtRu(N)Cl2] (1), which reacted with PPh3 to give the ruthenium(IV) phosphiniminato complex [LOEtRu(NPPh3)Cl2] (2). The cyclic voltammogram of 2 displays the RuIV/III couple at ca. 0 V vs ferrocenium/ferrocene. Treatment of 1 with Me3NO afforded [LOEtRu(NO)Cl2] (3), which reacted with Ag(OTf) (OTf- = triflate) to give the chloro-bridged tetranuclear ruthenium/silver complex [LOEtRu(NO)Cl2]2[Ag(OTf)]2 (4). Treatment of 1 with Na2S2O3 gave the thionitrosyl complex [LOEtRu(NS)Cl2] (5). The solid-state structures of 1−4 have been established by X-ray crystallography.
doi_str_mv 10.1021/ic7007683
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_68151784</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>68151784</sourcerecordid><originalsourceid>FETCH-LOGICAL-a332t-ac60f213cf95a1876eab8064620a0ce6f642567db2ddcb8f96e565e146c684963</originalsourceid><addsrcrecordid>eNptkEtOwzAURS0EgvIZsAGUCZ8OArYTvzhDqEpBVBTRghATy3WcYsgPO5Ha_bATNkaqVjBhdJ_0ju6VDkKHBJ8TTMmFURHGEfBgA3UIo9hnBL9sog7G7U0A4h2069w7xjgOQthGOyQCynhIO-i5n2lV27J6M5lR3mNTv-nCNPnZ823Xuze1NUnp9cq8yvS8zaKWpjDFzLvLvr8ac-q80Xwx04U3saYqE5l5QzOTRbKPtlKZOX2wzj30dN2f9G784Whw27sc-jIIaO1LBTilJFBpzCThEWg55RhCoFhipSGFkDKIkilNEjXlaQyaAdMkBAU8jCHYQyer3sqWn412tciNUzrLZKHLxgnghJGIhy3YXYHKls5ZnYrKmlzahSBYLCWKX4kte7Qubaa5Tv7ItbUW8FeAcbWe__6l_RAQBRETk4exuHoZDMf8NRbL8eMVL5UT72Vji9bJP8M_PG-HXA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>68151784</pqid></control><display><type>article</type><title>Electrophilic Ruthenium(VI) Nitrido Complex Containing Kläui's Oxygen Tripodal Ligand</title><source>American Chemical Society Journals</source><creator>Yi ; Lam, Tony C. H ; Sau, Yiu-Keung ; Zhang, Qian-Feng ; Williams, Ian D ; Leung, Wa-Hung</creator><creatorcontrib>Yi ; Lam, Tony C. H ; Sau, Yiu-Keung ; Zhang, Qian-Feng ; Williams, Ian D ; Leung, Wa-Hung</creatorcontrib><description>Treatment of [n-Bu4N][Ru(N)Cl4] with [AgLOEt] (LOEt - = [(η5-C5H5)Co{P(O)(OEt)2}3]-) afforded the ruthenium(VI) nitrido complex [LOEtRu(N)Cl2] (1), which reacted with PPh3 to give the ruthenium(IV) phosphiniminato complex [LOEtRu(NPPh3)Cl2] (2). The cyclic voltammogram of 2 displays the RuIV/III couple at ca. 0 V vs ferrocenium/ferrocene. Treatment of 1 with Me3NO afforded [LOEtRu(NO)Cl2] (3), which reacted with Ag(OTf) (OTf- = triflate) to give the chloro-bridged tetranuclear ruthenium/silver complex [LOEtRu(NO)Cl2]2[Ag(OTf)]2 (4). Treatment of 1 with Na2S2O3 gave the thionitrosyl complex [LOEtRu(NS)Cl2] (5). The solid-state structures of 1−4 have been established by X-ray crystallography.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/ic7007683</identifier><identifier>PMID: 17625842</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>Inorganic chemistry, 2007-08, Vol.46 (17), p.7193-7198</ispartof><rights>Copyright © 2007 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a332t-ac60f213cf95a1876eab8064620a0ce6f642567db2ddcb8f96e565e146c684963</citedby><cites>FETCH-LOGICAL-a332t-ac60f213cf95a1876eab8064620a0ce6f642567db2ddcb8f96e565e146c684963</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ic7007683$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ic7007683$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/17625842$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yi</creatorcontrib><creatorcontrib>Lam, Tony C. H</creatorcontrib><creatorcontrib>Sau, Yiu-Keung</creatorcontrib><creatorcontrib>Zhang, Qian-Feng</creatorcontrib><creatorcontrib>Williams, Ian D</creatorcontrib><creatorcontrib>Leung, Wa-Hung</creatorcontrib><title>Electrophilic Ruthenium(VI) Nitrido Complex Containing Kläui's Oxygen Tripodal Ligand</title><title>Inorganic chemistry</title><addtitle>Inorg. Chem</addtitle><description>Treatment of [n-Bu4N][Ru(N)Cl4] with [AgLOEt] (LOEt - = [(η5-C5H5)Co{P(O)(OEt)2}3]-) afforded the ruthenium(VI) nitrido complex [LOEtRu(N)Cl2] (1), which reacted with PPh3 to give the ruthenium(IV) phosphiniminato complex [LOEtRu(NPPh3)Cl2] (2). The cyclic voltammogram of 2 displays the RuIV/III couple at ca. 0 V vs ferrocenium/ferrocene. Treatment of 1 with Me3NO afforded [LOEtRu(NO)Cl2] (3), which reacted with Ag(OTf) (OTf- = triflate) to give the chloro-bridged tetranuclear ruthenium/silver complex [LOEtRu(NO)Cl2]2[Ag(OTf)]2 (4). Treatment of 1 with Na2S2O3 gave the thionitrosyl complex [LOEtRu(NS)Cl2] (5). The solid-state structures of 1−4 have been established by X-ray crystallography.</description><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNptkEtOwzAURS0EgvIZsAGUCZ8OArYTvzhDqEpBVBTRghATy3WcYsgPO5Ha_bATNkaqVjBhdJ_0ju6VDkKHBJ8TTMmFURHGEfBgA3UIo9hnBL9sog7G7U0A4h2069w7xjgOQthGOyQCynhIO-i5n2lV27J6M5lR3mNTv-nCNPnZ823Xuze1NUnp9cq8yvS8zaKWpjDFzLvLvr8ac-q80Xwx04U3saYqE5l5QzOTRbKPtlKZOX2wzj30dN2f9G784Whw27sc-jIIaO1LBTilJFBpzCThEWg55RhCoFhipSGFkDKIkilNEjXlaQyaAdMkBAU8jCHYQyer3sqWn412tciNUzrLZKHLxgnghJGIhy3YXYHKls5ZnYrKmlzahSBYLCWKX4kte7Qubaa5Tv7ItbUW8FeAcbWe__6l_RAQBRETk4exuHoZDMf8NRbL8eMVL5UT72Vji9bJP8M_PG-HXA</recordid><startdate>20070820</startdate><enddate>20070820</enddate><creator>Yi</creator><creator>Lam, Tony C. H</creator><creator>Sau, Yiu-Keung</creator><creator>Zhang, Qian-Feng</creator><creator>Williams, Ian D</creator><creator>Leung, Wa-Hung</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20070820</creationdate><title>Electrophilic Ruthenium(VI) Nitrido Complex Containing Kläui's Oxygen Tripodal Ligand</title><author>Yi ; Lam, Tony C. H ; Sau, Yiu-Keung ; Zhang, Qian-Feng ; Williams, Ian D ; Leung, Wa-Hung</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a332t-ac60f213cf95a1876eab8064620a0ce6f642567db2ddcb8f96e565e146c684963</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yi</creatorcontrib><creatorcontrib>Lam, Tony C. H</creatorcontrib><creatorcontrib>Sau, Yiu-Keung</creatorcontrib><creatorcontrib>Zhang, Qian-Feng</creatorcontrib><creatorcontrib>Williams, Ian D</creatorcontrib><creatorcontrib>Leung, Wa-Hung</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yi</au><au>Lam, Tony C. H</au><au>Sau, Yiu-Keung</au><au>Zhang, Qian-Feng</au><au>Williams, Ian D</au><au>Leung, Wa-Hung</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrophilic Ruthenium(VI) Nitrido Complex Containing Kläui's Oxygen Tripodal Ligand</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2007-08-20</date><risdate>2007</risdate><volume>46</volume><issue>17</issue><spage>7193</spage><epage>7198</epage><pages>7193-7198</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>Treatment of [n-Bu4N][Ru(N)Cl4] with [AgLOEt] (LOEt - = [(η5-C5H5)Co{P(O)(OEt)2}3]-) afforded the ruthenium(VI) nitrido complex [LOEtRu(N)Cl2] (1), which reacted with PPh3 to give the ruthenium(IV) phosphiniminato complex [LOEtRu(NPPh3)Cl2] (2). The cyclic voltammogram of 2 displays the RuIV/III couple at ca. 0 V vs ferrocenium/ferrocene. Treatment of 1 with Me3NO afforded [LOEtRu(NO)Cl2] (3), which reacted with Ag(OTf) (OTf- = triflate) to give the chloro-bridged tetranuclear ruthenium/silver complex [LOEtRu(NO)Cl2]2[Ag(OTf)]2 (4). Treatment of 1 with Na2S2O3 gave the thionitrosyl complex [LOEtRu(NS)Cl2] (5). The solid-state structures of 1−4 have been established by X-ray crystallography.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>17625842</pmid><doi>10.1021/ic7007683</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0020-1669
ispartof Inorganic chemistry, 2007-08, Vol.46 (17), p.7193-7198
issn 0020-1669
1520-510X
language eng
recordid cdi_proquest_miscellaneous_68151784
source American Chemical Society Journals
title Electrophilic Ruthenium(VI) Nitrido Complex Containing Kläui's Oxygen Tripodal Ligand
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T20%3A13%3A56IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Electrophilic%20Ruthenium(VI)%20Nitrido%20Complex%20Containing%20Kl%C3%A4ui's%20Oxygen%20Tripodal%20Ligand&rft.jtitle=Inorganic%20chemistry&rft.au=Yi&rft.date=2007-08-20&rft.volume=46&rft.issue=17&rft.spage=7193&rft.epage=7198&rft.pages=7193-7198&rft.issn=0020-1669&rft.eissn=1520-510X&rft_id=info:doi/10.1021/ic7007683&rft_dat=%3Cproquest_cross%3E68151784%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=68151784&rft_id=info:pmid/17625842&rfr_iscdi=true