Total Synthesis of Solandelactones E and F, Homoeicosanoids from the Hydroid Solanderia secunda

Asymmetric total syntheses of solandelactones E and F confirmed that hydroxyl configuration at C11 in these oxylipins had been misassigned and that the stereochemistry at this center should be reversed. Key steps in the synthesis involved a Nagao asymmetric acetate aldol reaction, a directed Simmons...

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Veröffentlicht in:	Organic letters 2007-08, Vol.9 (17), p.3481-3483
Hauptverfasser:	White, James D, Martin, William H. C, Lincoln, Christopher, Yang, Jongtae
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetates - chemistry Aldehydes - chemistry Cyclopropanes - chemistry Eicosanoids - chemical synthesis Eicosanoids - chemistry Lactones - chemical synthesis Lactones - chemistry Marine Biology Molecular Structure Stereoisomerism
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