Methane Oxidation by Aqueous Osmium Tetroxide and Sodium Periodate: Inhibition of Methanol Oxidation by Methane

Cast in a new role: Aqueous solutions of OsO4 and NaIO4 oxidize methane to methanol under very mild conditions (see scheme). The generated methanol is preserved over 5 days at 50 °C, although it is more readily oxidized than methane in separate experiments. Remarkably, methanol oxidation by aqueous...

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Veröffentlicht in:	Angewandte Chemie International Edition 2006-11, Vol.45 (44), p.7433-7436
Hauptverfasser:	Osako, Takao, Watson, Eric J., Dehestani, Ahmad, Bales, Brian C., Mayer, James M.
Format:	Artikel
Sprache:	eng
Schlagworte:	inhibition methane Methane - chemistry methanol Methanol - chemistry osmium Osmium Tetroxide - chemistry oxidation Oxidation-Reduction Periodic Acid - chemistry Solutions Water
Online-Zugang:	Volltext
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