A Tosylimido Analogue of a Nonheme Oxoiron(IV) Complex

High‐valent versatility: N4Py is a versatile pentadentate ligand demonstrated to stabilize both high‐valent oxo and imido compounds. The [FeIV(NTs)(N4Py)]2+ complex (see DFT‐optimized structure) has been characterized spectroscopically and formulated as having an S=1 iron(IV) center with an FeN bon...

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Veröffentlicht in:	Angewandte Chemie International Edition 2006-11, Vol.45 (44), p.7394-7397
Hauptverfasser:	Klinker, Eric J., Jackson, Timothy A., Jensen, Michael P., Stubna, Audria, Juhász, Gergely, Bominaar, Emile L., Münck, Eckard, Que Jr, Lawrence
Format:	Artikel
Sprache:	eng
Schlagworte:	bioinorganic chemistry density functional calculations Heme - chemistry imido ligands iron Iron - chemistry Magnetic Resonance Spectroscopy Molecular Structure Mössbauer spectroscopy Pyridines - chemistry
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container_title	Angewandte Chemie International Edition
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creator	Klinker, Eric J. Jackson, Timothy A. Jensen, Michael P. Stubna, Audria Juhász, Gergely Bominaar, Emile L. Münck, Eckard Que Jr, Lawrence
description	High‐valent versatility: N4Py is a versatile pentadentate ligand demonstrated to stabilize both high‐valent oxo and imido compounds. The [FeIV(NTs)(N4Py)]2+ complex (see DFT‐optimized structure) has been characterized spectroscopically and formulated as having an S=1 iron(IV) center with an FeN bond (1.73 Å) that is longer than the FeO bond of its oxo analogue (1.65 Å).
doi_str_mv	10.1002/anie.200602799
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subjects	bioinorganic chemistry density functional calculations Heme - chemistry imido ligands iron Iron - chemistry Magnetic Resonance Spectroscopy Molecular Structure Mössbauer spectroscopy Pyridines - chemistry
title	A Tosylimido Analogue of a Nonheme Oxoiron(IV) Complex
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