Photolysis of the HNO Adduct of Myoglobin:  Transient Generation of the Aminoxyl Radical

The photolysis of the HNO-myoglobin adduct has been followed by transient absorption experiments down to the nanosecond time scale. A unique transient assignable to generation of an FeIII/HNO- geminate pair is observed; the transient loss of this absorbance trace, assignable to the recombination, is...

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Veröffentlicht in:	Journal of the American Chemical Society 2007-08, Vol.129 (31), p.9590-9591
Hauptverfasser:	Pervitsky, Dmitry, Immoos, Chad, van der Veer, Wytze, Farmer, Patrick J
Format:	Artikel
Sprache:	eng
Schlagworte:	Amination Free Radicals - chemistry Hydrogen - chemistry Molybdenum - chemistry Myoglobin - chemistry Nitric Oxide - chemistry Oxidation-Reduction Photolysis
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