Spectroscopic studies on [(DD18C6H 2)(HPA) 2](PA) 2 and [(DD18C6H 2)(DDQ) 2](DDQH) 2 formed in the reaction of N, N′-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane with HPA and DDQ

The interaction of the mixed oxygen–nitrogen cyclic base, N, N′-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane (DD18C6) with π-acceptors such as picric acid (HPA) and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) has been studied spectrophotometrically in chloroform at 25 °C. The results ob...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Molecular and biomolecular spectroscopy, 2005-09, Vol.61 (11), p.2708-2712
Hauptverfasser:	Teleb, Said M., Gaballa, Akmal S., Elmosallamy, M.A.F., Nour, El-Metwally
Format:	Artikel
Sprache:	eng
Schlagworte:	1H NMR Aza Compounds - chemistry Benzoquinones - chemistry Charge–transfer Diazacrown ether Electrons Heterocyclic Compounds, 1-Ring - chemistry Magnetic Resonance Spectroscopy Molecular Structure Picrates - chemistry Spectrophotometry, Infrared Titrimetry UV–vis spectra π-Acceptors
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	2712
container_issue	11
container_start_page	2708
container_title	Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
container_volume	61
creator	Teleb, Said M. Gaballa, Akmal S. Elmosallamy, M.A.F. Nour, El-Metwally
description	The interaction of the mixed oxygen–nitrogen cyclic base, N, N′-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane (DD18C6) with π-acceptors such as picric acid (HPA) and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) has been studied spectrophotometrically in chloroform at 25 °C. The results obtained indicate the formation of 1:4 charge–transfer complexes with the general formula (DD18C6)(acceptor) 4. The electronic and infrared spectra of charge–transfer complexes along with the 1H NMR spectra were recorded and discussed. Based on the data obtained, the complexes were formulated as [(DD18C6H 2)(HPA) 2](PA) 2 and [(DD18C6H 2)(DDQ) 2](DDQH) 2. A general mechanism explaining the formation of the DDQ complex has been suggested.
doi_str_mv	10.1016/j.saa.2004.10.014
format	Article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_68079485</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S1386142504005232</els_id><sourcerecordid>68079485</sourcerecordid><originalsourceid>FETCH-LOGICAL-c266t-c1d5a415e4036d7d9247a2d31458618d409021077800cd5c60a4221b16a6cfc13</originalsourceid><addsrcrecordid>eNp9kc9uEzEQxn0A0VJ4AC7IJ5RKu2HG6_VuxKlKKEGqCgg4IWQ5tld1tFmntgOkpz4Td16GJ8H5IyEunEb2fPP58_wIeYYwRkDxcjmOSo0ZAM_nMSB_QE6xakWJnNUn5HGMSwDAlsEjcoICeAWiOSW_Pq6tTsFH7ddO05g2xtlI_UC_jGYzbKdiTtn5aP7-4pyyr6N9oWow_7Znsw_7dq7znaDzYWUNdQNNN5YGq3Ry2dJ39Lqg17_vf5bGLexwt-1LLHiBUGBVJpuC8j9U2RQoskDdKb3Vvfc6KWO1Giz97tINzVn2CfJjT8jDTvXRPj3WM_L58vWn6by8evfm7fTiqtRMiFRqNLXiWFsOlTCNmTDeKGYq5HUrsDUcJsAQmqYF0KbWAhRnDBcolNCdxuqMvDj4roO_3diY5MpFbfs-h_KbKEULzYS3dRbiQajzSmOwnVwHt1JhKxHkjpNcysxJ7jjtrjKnPPP8aL5Z5K39nThCyoJXB4HNX_zmbJBROztoa1zI8KTx7j_2fwD2MZ0d</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>68079485</pqid></control><display><type>article</type><title>Spectroscopic studies on [(DD18C6H 2)(HPA) 2](PA) 2 and [(DD18C6H 2)(DDQ) 2](DDQH) 2 formed in the reaction of N, N′-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane with HPA and DDQ</title><source>MEDLINE</source><source>ScienceDirect Journals (5 years ago - present)</source><creator>Teleb, Said M. ; Gaballa, Akmal S. ; Elmosallamy, M.A.F. ; Nour, El-Metwally</creator><creatorcontrib>Teleb, Said M. ; Gaballa, Akmal S. ; Elmosallamy, M.A.F. ; Nour, El-Metwally</creatorcontrib><description>The interaction of the mixed oxygen–nitrogen cyclic base, N, N′-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane (DD18C6) with π-acceptors such as picric acid (HPA) and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) has been studied spectrophotometrically in chloroform at 25 °C. The results obtained indicate the formation of 1:4 charge–transfer complexes with the general formula (DD18C6)(acceptor) 4. The electronic and infrared spectra of charge–transfer complexes along with the 1H NMR spectra were recorded and discussed. Based on the data obtained, the complexes were formulated as [(DD18C6H 2)(HPA) 2](PA) 2 and [(DD18C6H 2)(DDQ) 2](DDQH) 2. A general mechanism explaining the formation of the DDQ complex has been suggested.</description><identifier>ISSN: 1386-1425</identifier><identifier>DOI: 10.1016/j.saa.2004.10.014</identifier><identifier>PMID: 16043067</identifier><language>eng</language><publisher>England: Elsevier B.V</publisher><subject>1H NMR ; Aza Compounds - chemistry ; Benzoquinones - chemistry ; Charge–transfer ; Diazacrown ether ; Electrons ; Heterocyclic Compounds, 1-Ring - chemistry ; Magnetic Resonance Spectroscopy ; Molecular Structure ; Picrates - chemistry ; Spectrophotometry, Infrared ; Titrimetry ; UV–vis spectra ; π-Acceptors</subject><ispartof>Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 2005-09, Vol.61 (11), p.2708-2712</ispartof><rights>2004</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c266t-c1d5a415e4036d7d9247a2d31458618d409021077800cd5c60a4221b16a6cfc13</citedby><cites>FETCH-LOGICAL-c266t-c1d5a415e4036d7d9247a2d31458618d409021077800cd5c60a4221b16a6cfc13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.saa.2004.10.014$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,778,782,3539,27911,27912,45982</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/16043067$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Teleb, Said M.</creatorcontrib><creatorcontrib>Gaballa, Akmal S.</creatorcontrib><creatorcontrib>Elmosallamy, M.A.F.</creatorcontrib><creatorcontrib>Nour, El-Metwally</creatorcontrib><title>Spectroscopic studies on [(DD18C6H 2)(HPA) 2](PA) 2 and [(DD18C6H 2)(DDQ) 2](DDQH) 2 formed in the reaction of N, N′-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane with HPA and DDQ</title><title>Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy</title><addtitle>Spectrochim Acta A Mol Biomol Spectrosc</addtitle><description>The interaction of the mixed oxygen–nitrogen cyclic base, N, N′-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane (DD18C6) with π-acceptors such as picric acid (HPA) and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) has been studied spectrophotometrically in chloroform at 25 °C. The results obtained indicate the formation of 1:4 charge–transfer complexes with the general formula (DD18C6)(acceptor) 4. The electronic and infrared spectra of charge–transfer complexes along with the 1H NMR spectra were recorded and discussed. Based on the data obtained, the complexes were formulated as [(DD18C6H 2)(HPA) 2](PA) 2 and [(DD18C6H 2)(DDQ) 2](DDQH) 2. A general mechanism explaining the formation of the DDQ complex has been suggested.</description><subject>1H NMR</subject><subject>Aza Compounds - chemistry</subject><subject>Benzoquinones - chemistry</subject><subject>Charge–transfer</subject><subject>Diazacrown ether</subject><subject>Electrons</subject><subject>Heterocyclic Compounds, 1-Ring - chemistry</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>Molecular Structure</subject><subject>Picrates - chemistry</subject><subject>Spectrophotometry, Infrared</subject><subject>Titrimetry</subject><subject>UV–vis spectra</subject><subject>π-Acceptors</subject><issn>1386-1425</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kc9uEzEQxn0A0VJ4AC7IJ5RKu2HG6_VuxKlKKEGqCgg4IWQ5tld1tFmntgOkpz4Td16GJ8H5IyEunEb2fPP58_wIeYYwRkDxcjmOSo0ZAM_nMSB_QE6xakWJnNUn5HGMSwDAlsEjcoICeAWiOSW_Pq6tTsFH7ddO05g2xtlI_UC_jGYzbKdiTtn5aP7-4pyyr6N9oWow_7Znsw_7dq7znaDzYWUNdQNNN5YGq3Ry2dJ39Lqg17_vf5bGLexwt-1LLHiBUGBVJpuC8j9U2RQoskDdKb3Vvfc6KWO1Giz97tINzVn2CfJjT8jDTvXRPj3WM_L58vWn6by8evfm7fTiqtRMiFRqNLXiWFsOlTCNmTDeKGYq5HUrsDUcJsAQmqYF0KbWAhRnDBcolNCdxuqMvDj4roO_3diY5MpFbfs-h_KbKEULzYS3dRbiQajzSmOwnVwHt1JhKxHkjpNcysxJ7jjtrjKnPPP8aL5Z5K39nThCyoJXB4HNX_zmbJBROztoa1zI8KTx7j_2fwD2MZ0d</recordid><startdate>200509</startdate><enddate>200509</enddate><creator>Teleb, Said M.</creator><creator>Gaballa, Akmal S.</creator><creator>Elmosallamy, M.A.F.</creator><creator>Nour, El-Metwally</creator><general>Elsevier B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>200509</creationdate><title>Spectroscopic studies on [(DD18C6H 2)(HPA) 2](PA) 2 and [(DD18C6H 2)(DDQ) 2](DDQH) 2 formed in the reaction of N, N′-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane with HPA and DDQ</title><author>Teleb, Said M. ; Gaballa, Akmal S. ; Elmosallamy, M.A.F. ; Nour, El-Metwally</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c266t-c1d5a415e4036d7d9247a2d31458618d409021077800cd5c60a4221b16a6cfc13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>1H NMR</topic><topic>Aza Compounds - chemistry</topic><topic>Benzoquinones - chemistry</topic><topic>Charge–transfer</topic><topic>Diazacrown ether</topic><topic>Electrons</topic><topic>Heterocyclic Compounds, 1-Ring - chemistry</topic><topic>Magnetic Resonance Spectroscopy</topic><topic>Molecular Structure</topic><topic>Picrates - chemistry</topic><topic>Spectrophotometry, Infrared</topic><topic>Titrimetry</topic><topic>UV–vis spectra</topic><topic>π-Acceptors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Teleb, Said M.</creatorcontrib><creatorcontrib>Gaballa, Akmal S.</creatorcontrib><creatorcontrib>Elmosallamy, M.A.F.</creatorcontrib><creatorcontrib>Nour, El-Metwally</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Teleb, Said M.</au><au>Gaballa, Akmal S.</au><au>Elmosallamy, M.A.F.</au><au>Nour, El-Metwally</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Spectroscopic studies on [(DD18C6H 2)(HPA) 2](PA) 2 and [(DD18C6H 2)(DDQ) 2](DDQH) 2 formed in the reaction of N, N′-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane with HPA and DDQ</atitle><jtitle>Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy</jtitle><addtitle>Spectrochim Acta A Mol Biomol Spectrosc</addtitle><date>2005-09</date><risdate>2005</risdate><volume>61</volume><issue>11</issue><spage>2708</spage><epage>2712</epage><pages>2708-2712</pages><issn>1386-1425</issn><abstract>The interaction of the mixed oxygen–nitrogen cyclic base, N, N′-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane (DD18C6) with π-acceptors such as picric acid (HPA) and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) has been studied spectrophotometrically in chloroform at 25 °C. The results obtained indicate the formation of 1:4 charge–transfer complexes with the general formula (DD18C6)(acceptor) 4. The electronic and infrared spectra of charge–transfer complexes along with the 1H NMR spectra were recorded and discussed. Based on the data obtained, the complexes were formulated as [(DD18C6H 2)(HPA) 2](PA) 2 and [(DD18C6H 2)(DDQ) 2](DDQH) 2. A general mechanism explaining the formation of the DDQ complex has been suggested.</abstract><cop>England</cop><pub>Elsevier B.V</pub><pmid>16043067</pmid><doi>10.1016/j.saa.2004.10.014</doi><tpages>5</tpages></addata></record>
fulltext	fulltext
identifier	ISSN: 1386-1425
ispartof	Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 2005-09, Vol.61 (11), p.2708-2712
issn	1386-1425
language	eng
recordid	cdi_proquest_miscellaneous_68079485
source	MEDLINE; ScienceDirect Journals (5 years ago - present)
subjects	1H NMR Aza Compounds - chemistry Benzoquinones - chemistry Charge–transfer Diazacrown ether Electrons Heterocyclic Compounds, 1-Ring - chemistry Magnetic Resonance Spectroscopy Molecular Structure Picrates - chemistry Spectrophotometry, Infrared Titrimetry UV–vis spectra π-Acceptors
title	Spectroscopic studies on [(DD18C6H 2)(HPA) 2](PA) 2 and [(DD18C6H 2)(DDQ) 2](DDQH) 2 formed in the reaction of N, N′-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane with HPA and DDQ
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-15T10%3A30%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Spectroscopic%20studies%20on%20%5B(DD18C6H%202)(HPA)%202%5D(PA)%202%20and%20%5B(DD18C6H%202)(DDQ)%202%5D(DDQH)%202%20formed%20in%20the%20reaction%20of%20N,%20N%E2%80%B2-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane%20with%20HPA%20and%20DDQ&rft.jtitle=Spectrochimica%20acta.%20Part%20A,%20Molecular%20and%20biomolecular%20spectroscopy&rft.au=Teleb,%20Said%20M.&rft.date=2005-09&rft.volume=61&rft.issue=11&rft.spage=2708&rft.epage=2712&rft.pages=2708-2712&rft.issn=1386-1425&rft_id=info:doi/10.1016/j.saa.2004.10.014&rft_dat=%3Cproquest_cross%3E68079485%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=68079485&rft_id=info:pmid/16043067&rft_els_id=S1386142504005232&rfr_iscdi=true