Interpretation of the excess adsorption isotherms of organic eluent components on the surface of reversed-phase phenyl modified adsorbents
The adsorption of three organic eluent components (acetonitrile, methanol, and tetrahydrofuran) from water were measured on four phenyl-type bonded phases using the minor disturbance method. The thicknesses of organic layer enriched above the phenyl-type bonded ligands were assessed and interpreted....
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| Veröffentlicht in: | Journal of Chromatography A 2005-08, Vol.1082 (2), p.158-165 |
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| container_end_page | 165 |
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| container_issue | 2 |
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| container_title | Journal of Chromatography A |
| container_volume | 1082 |
| creator | Chan, F. Yeung, L.S. LoBrutto, R. Kazakevich, Y.V. |
| description | The adsorption of three organic eluent components (acetonitrile, methanol, and tetrahydrofuran) from water were measured on four phenyl-type bonded phases using the minor disturbance method. The thicknesses of organic layer enriched above the phenyl-type bonded ligands were assessed and interpreted. Acetonitrile and tetrahydrofuran showed multilayer formation while methanol showed monomolecular adsorption. These results were compared to those obtained on alkyl bonded phases. |
| doi_str_mv | 10.1016/j.chroma.2005.05.078 |
| format | Article |
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The thicknesses of organic layer enriched above the phenyl-type bonded ligands were assessed and interpreted. Acetonitrile and tetrahydrofuran showed multilayer formation while methanol showed monomolecular adsorption. These results were compared to those obtained on alkyl bonded phases.</description><subject>Acetonitriles - chemistry</subject><subject>Adsorption</subject><subject>Analytical chemistry</subject><subject>Chemistry</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>Chromatography, High Pressure Liquid - methods</subject><subject>Exact sciences and technology</subject><subject>Furans - chemistry</subject><subject>Methanol - chemistry</subject><subject>Other chromatographic methods</subject><subject>Phenyl-type bonded phases</subject><subject>Reversed-phase</subject><subject>Water - chemistry</subject><issn>0021-9673</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kE2L1TAUhrNQnHH0H4h0o7veSfqRtBtBBj8GBtzoOqQnp95c2qSe0w7OX_BX204v6GrgQALv856ER4g3Sh6UVPr6dIAjpdEdCinrwzameSYupSxU3mpTXoiXzCcplZGmeCEulJZlXdbmUvy5jTPSRDi7OaSYpT6bj5jhb0DmzHlOND0GgdMa0MgbkuiniwEyHBaMcwZpnFJcb2sYH_u8UO8AN5bwHonR59PRMWbTEePDkI3Jhz6g35_otu4r8bx3A-Pr83klfnz-9P3ma3737cvtzce7HKpaz3kP4H2DiBoKVE551bboW9C6LDrZepRaucJhW3tXugY732rESkLfSWMqU16J9_veidKvBXm2Y2DAYXAR08JWN1IXdaFXsNpBoMRM2NuJwujowSppN-_2ZHfvdvNutzHNWnt73r90I_p_pbP0FXh3BhyDG3pyEQL_xzWtKctq5T7sHK427gOSZQgYAX0ghNn6FJ7-yV-Bf6o4</recordid><startdate>20050805</startdate><enddate>20050805</enddate><creator>Chan, F.</creator><creator>Yeung, L.S.</creator><creator>LoBrutto, R.</creator><creator>Kazakevich, Y.V.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20050805</creationdate><title>Interpretation of the excess adsorption isotherms of organic eluent components on the surface of reversed-phase phenyl modified adsorbents</title><author>Chan, F. ; Yeung, L.S. ; LoBrutto, R. ; Kazakevich, Y.V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c456t-fccdd8eee6c2e1a1d199ed9c6632b09de061a2ae95da3a8ebd96ee40cfb077473</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Acetonitriles - chemistry</topic><topic>Adsorption</topic><topic>Analytical chemistry</topic><topic>Chemistry</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>Chromatography, High Pressure Liquid - methods</topic><topic>Exact sciences and technology</topic><topic>Furans - chemistry</topic><topic>Methanol - chemistry</topic><topic>Other chromatographic methods</topic><topic>Phenyl-type bonded phases</topic><topic>Reversed-phase</topic><topic>Water - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chan, F.</creatorcontrib><creatorcontrib>Yeung, L.S.</creatorcontrib><creatorcontrib>LoBrutto, R.</creatorcontrib><creatorcontrib>Kazakevich, Y.V.</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of Chromatography A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chan, F.</au><au>Yeung, L.S.</au><au>LoBrutto, R.</au><au>Kazakevich, Y.V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Interpretation of the excess adsorption isotherms of organic eluent components on the surface of reversed-phase phenyl modified adsorbents</atitle><jtitle>Journal of Chromatography A</jtitle><addtitle>J Chromatogr A</addtitle><date>2005-08-05</date><risdate>2005</risdate><volume>1082</volume><issue>2</issue><spage>158</spage><epage>165</epage><pages>158-165</pages><issn>0021-9673</issn><coden>JOCRAM</coden><abstract>The adsorption of three organic eluent components (acetonitrile, methanol, and tetrahydrofuran) from water were measured on four phenyl-type bonded phases using the minor disturbance method. 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| ispartof | Journal of Chromatography A, 2005-08, Vol.1082 (2), p.158-165 |
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| language | eng |
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| source | MEDLINE; ScienceDirect Journals (5 years ago - present) |
| subjects | Acetonitriles - chemistry Adsorption Analytical chemistry Chemistry Chromatographic methods and physical methods associated with chromatography Chromatography, High Pressure Liquid - methods Exact sciences and technology Furans - chemistry Methanol - chemistry Other chromatographic methods Phenyl-type bonded phases Reversed-phase Water - chemistry |
| title | Interpretation of the excess adsorption isotherms of organic eluent components on the surface of reversed-phase phenyl modified adsorbents |
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