Synthetic and Structural Studies of Cyclodistib(V)azanes

High-yielding syntheses of complexes based around the cyclodistibazane (Sb2N2) core are described from the reaction of organoantimony(V) chlorides with varying stoichiometric amounts of lithiated primary amines, LiN(H)R. Thus, mixing Ph3SbCl2 with 2 equiv of LiN(H)R (R = CH2Ph) produces Ph3Sb(μ-NR)2...

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Veröffentlicht in:	Inorganic chemistry 2005-07, Vol.44 (15), p.5495-5500
Hauptverfasser:	Copsey, May C, Gallon, Sabrina B, Grocott, Sara K, Jeffery, John C, Russell, Christopher A, Slattery, John M
Format:	Artikel
Sprache:	eng
Schlagworte:	Antimony - chemistry Crystallography, X-Ray Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry
Online-Zugang:	Volltext
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