Switching of the Electronic Communication between Two {Ru(trpy)(bpy)} (trpy = 2,2‘:6‘,2‘ ‘-Terpyridine and bpy = 2,2‘-Bipyridine) Centers by Protonation on the Bridging Dimercaptothiadiazolato Ligand

A stable Ru(II)/Ru(III) mixed-valence state was observed in acetonitrile for the ruthenium binuclear complex bridged by dimercaptothiadiazolate (ΔE 1/2 = 220 mV for Ru2(II,II)/Ru2(II,III) and Ru2(II,III)/Ru2(III,III) processes; K com = 5.3 × 103). Upon protonation of the bridging ligand by the addit...

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Veröffentlicht in:	Inorganic chemistry 2005-07, Vol.44 (15), p.5206-5208
Hauptverfasser:	Tannai, Hidenori, Tsuge, Kiyoshi, Sasaki, Yoichi
Format:	Artikel
Sprache:	eng
Schlagworte:	Bridged-Ring Compounds - chemistry Crystallography, X-Ray Dimercaprol - chemistry Electrons Ligands Models, Molecular Organometallic Compounds - chemistry Protons Ruthenium - chemistry Thiadiazoles - chemistry
Online-Zugang:	Volltext
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