Catalytic Removal of N-Allyloxycarbonyl Groups Using the [CpRu(IV)(π-C3H5)(2-quinolinecarboxylato)]PF6 Complex. A New Efficient Deprotecting Method in Peptide Synthesis

A variety of amines including even sterically less demanding and highly nucleophilic secondary amines have been efficiently deprotected without decarboxylative N-allylation from the corresponding N-allyloxycarbonyl (N-AOC) compounds by using a catalytic amount of [CpRu(IV)(π-C3H5)(2-quinolinecarboxy...

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Veröffentlicht in:	Journal of organic chemistry 2006-06, Vol.71 (12), p.4682-4684
Hauptverfasser:	Tanaka, Shinji, Saburi, Hajime, Murase, Takanori, Yoshimura, Masahiro, Kitamura, Masato
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines - chemistry Catalysis Chemistry Collagen Exact sciences and technology Methods Oligopeptides - chemical synthesis Organic chemistry Peptides Peptides - chemical synthesis Preparations and properties
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