A Carbocyclic Carbene as an Efficient Catalyst Ligand for CC Coupling Reactions
A new player on the field: Carbocyclic carbenes are potentially better control ligands than N‐heterocyclic carbenes (NHCs) in catalyzed CC coupling reactions. PdII complexes of cycloheptatrienylidene (see picture), which are readily prepared, thermally stable, and highly stable towards acid, are as...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2006-06, Vol.45 (23), p.3859-3862 |
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| container_issue | 23 |
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| container_title | Angewandte Chemie International Edition |
| container_volume | 45 |
| creator | Herrmann, Wolfgang A. Öfele, Karl Schneider, Sabine K. Herdtweck, Eberhardt Hoffmann, Stephan D. |
| description | A new player on the field: Carbocyclic carbenes are potentially better control ligands than N‐heterocyclic carbenes (NHCs) in catalyzed CC coupling reactions. PdII complexes of cycloheptatrienylidene (see picture), which are readily prepared, thermally stable, and highly stable towards acid, are as effective as the familiar NHC complexes in Suzuki and Heck reactions or perform even better. |
| doi_str_mv | 10.1002/anie.200503589 |
| format | Article |
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| language | eng |
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| source | Wiley Online Library All Journals |
| subjects | carbenes carbocycles CC coupling homogeneous catalysis palladium |
| title | A Carbocyclic Carbene as an Efficient Catalyst Ligand for CC Coupling Reactions |
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