Self-Assembled Monolayers and Preorganization of Organosilanes Prior to Surface Grafting onto Silica:  A Quantum Mechanical Study

Quantum chemical calculations have been carried out on the grafting of chain organosilane compounds on SiO2-hydroxylated solid surfaces. It is shown that a single molecule interacting with the surface lies flat to it, inhibiting further homogeneous film growth. This adsorption exhibits two molecule/...

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Veröffentlicht in:	Journal of the American Chemical Society 2005-07, Vol.127 (27), p.9776-9780
Hauptverfasser:	Dkhissi, A, Estève, A, Jeloaica, L, Estève, D, Rouhani, M. Djafari
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorption and desorption kinetics evaporation and condensation Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Physics Solid-fluid interfaces Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties)
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