The Zintl Ion [Pb10]2−: A Rare Example of a Homoatomic closo Cluster

The Zintl Ion [Pb10]2−: A Rare Example of a Homoatomic closo Cluster

Closed encounters: A closed deltahedral homoatomic cluster, [Pb10]2−, is structurally characterized. When this “empty” cluster is considered together with the recently published filled cluster [Ni@Pb10]2−, a striking parallel to the fullerenes emerges: Zintl ions form polyhedral cages that can enclo...

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Veröffentlicht in:Angewandte Chemie International Edition 2006-05, Vol.45 (21), p.3459-3462
Hauptverfasser: Spiekermann, Annette, Hoffmann, Stephan D., Fässler, Thomas F.
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Sprache:eng
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cluster compounds
cryptands
lead
Wade's rules
Zintl anions
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creator Spiekermann, Annette
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Fässler, Thomas F.
description Closed encounters: A closed deltahedral homoatomic cluster, [Pb10]2−, is structurally characterized. When this “empty” cluster is considered together with the recently published filled cluster [Ni@Pb10]2−, a striking parallel to the fullerenes emerges: Zintl ions form polyhedral cages that can enclose a central atom without any major structural alterations.
doi_str_mv 10.1002/anie.200503916
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subjects cluster compounds
cryptands
lead
Wade's rules
Zintl anions
title The Zintl Ion [Pb10]2−: A Rare Example of a Homoatomic closo Cluster
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