Copper-Catalyzed Stereospecific N-Allenylations of Amides. Syntheses of Optically Enriched Chiral Allenamides

Copper-Catalyzed Stereospecific N-Allenylations of Amides. Syntheses of Optically Enriched Chiral Allenamides

Syntheses of chiral allenamides via a stereospecific amidation of optically enriched allenyl iodides using catalytic copper(I) salt and N,N ‘-dimethylethylene-diamine are described here.

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Veröffentlicht in:Organic letters 2005-07, Vol.7 (14), p.3081-3084
Hauptverfasser: Shen, Lichun, Hsung, Richard P, Zhang, Yanshi, Antoline, Jennifer E, Zhang, Xuejun
Format: Artikel
Sprache:eng
Schlagworte:
Amides - chemical synthesis
Amides - chemistry
Catalysis
Copper - chemistry
Indicators and Reagents
Molecular Structure
Stereoisomerism
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Beschreibung
Zusammenfassung:Syntheses of chiral allenamides via a stereospecific amidation of optically enriched allenyl iodides using catalytic copper(I) salt and N,N ‘-dimethylethylene-diamine are described here.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol051094q