α-Hydroxy Cyclopentenones from α-Diketones

Metalloenolates derived from α,β-unsaturated α-diketones undergo cyclization to α-hydroxy cyclopentenones. This is apparently the first reported Nazarov reaction that takes place in the presence of base.

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Veröffentlicht in:	Organic letters 2005-06, Vol.7 (13), p.2771-2774
Hauptverfasser:	Batson, William A, Sethumadhavan, Divakaramenon, Tius, Marcus A
Format:	Artikel
Sprache:	eng
Schlagworte:	Cyclization Cyclopentanes - analysis Cyclopentanes - chemical synthesis Ketones - chemistry Molecular Structure Stereoisomerism
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description	Metalloenolates derived from α,β-unsaturated α-diketones undergo cyclization to α-hydroxy cyclopentenones. This is apparently the first reported Nazarov reaction that takes place in the presence of base.
doi_str_mv	10.1021/ol050970x
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source	ACS Publications; MEDLINE
subjects	Cyclization Cyclopentanes - analysis Cyclopentanes - chemical synthesis Ketones - chemistry Molecular Structure Stereoisomerism
title	α-Hydroxy Cyclopentenones from α-Diketones
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