Catalytic Enantioselective Allylation of Ketones via a Chiral Indium(III) Complex

Catalytic Enantioselective Allylation of Ketones via a Chiral Indium(III) Complex

A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributylstannanes to ketones. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic ketones resulted in good yields and high enantioselectivities (up to 92% ee).

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Veröffentlicht in:Organic letters 2005-06, Vol.7 (13), p.2743-2745
Hauptverfasser: Teo, Yong-Chua, Goh, Joshua-Daniel, Loh, Teck-Peng
Format: Artikel
Sprache:eng
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Zusammenfassung:A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributylstannanes to ketones. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic ketones resulted in good yields and high enantioselectivities (up to 92% ee).
ISSN:1523-7060
1523-7052
DOI:10.1021/ol051018n