Structures of Nonheme Oxoiron(IV) Complexes from X-ray Crystallography, NMR Spectroscopy, and DFT Calculations
Stabilizing the oxoiron(IV) unit: From a combination of X‐ray crystallography, NMR spectroscopy, and DFT calculations, the relative thermal stabilities of two oxoiron(IV) complexes with pentaaza ligands, such as that shown in the picture, can be ascribed to the number of pyridine rings that are orie...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2005-06, Vol.44 (24), p.3690-3694 |
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| container_issue | 24 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Klinker, Eric J. Kaizer, József Brennessel, William W. Woodrum, Nathaniel L. Cramer, Christopher J. Que Jr, Lawrence |
| description | Stabilizing the oxoiron(IV) unit: From a combination of X‐ray crystallography, NMR spectroscopy, and DFT calculations, the relative thermal stabilities of two oxoiron(IV) complexes with pentaaza ligands, such as that shown in the picture, can be ascribed to the number of pyridine rings that are oriented parallel to the FeO bond. (Fe pink, N blue, O red, C black.) |
| doi_str_mv | 10.1002/anie.200500485 |
| format | Article |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | bioinorganic chemistry Crystallography, X-Ray density functional calculations iron Iron - chemistry Magnetic Resonance Spectroscopy - methods Magnetic Resonance Spectroscopy - standards Models, Chemical Molecular Structure nitrogen heterocycles NMR spectroscopy Organometallic Compounds - chemistry Oxygen - chemistry Quantum Theory Reference Standards |
| title | Structures of Nonheme Oxoiron(IV) Complexes from X-ray Crystallography, NMR Spectroscopy, and DFT Calculations |
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