Selective Electrochemical Detection of Hydrogen Fluoride by Ambiphilic Ferrocene Derivatives

Appropriate linking of Lewis acidic and Lewis basic components—in this case boronic acid and tertiary amine functionalities—allows the construction of a robust organometallic receptor capable of selectively binding hydrogen fluoride. This system can differentiate between exposure to HF and to relate...

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Veröffentlicht in:	Angewandte Chemie International Edition 2005-06, Vol.44 (23), p.3606-3609
Hauptverfasser:	Bresner, Christopher, Aldridge, Simon, Fallis, Ian A., Jones, Cameron, Ooi, Li-Ling
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Sprache:	eng
Schlagworte:	boron electrochemistry metallocenes molecular recognition sensors
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creator	Bresner, Christopher Aldridge, Simon Fallis, Ian A. Jones, Cameron Ooi, Li-Ling
description	Appropriate linking of Lewis acidic and Lewis basic components—in this case boronic acid and tertiary amine functionalities—allows the construction of a robust organometallic receptor capable of selectively binding hydrogen fluoride. This system can differentiate between exposure to HF and to related acids, such as HCl, by providing opposing electrochemical responses (see picture).
doi_str_mv	10.1002/anie.200500527
format	Article
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title	Selective Electrochemical Detection of Hydrogen Fluoride by Ambiphilic Ferrocene Derivatives
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