New Air-Stable Catalysts for General and Efficient Suzuki−Miyaura Cross-Coupling Reactions of Heteroaryl Chlorides

New air-stable PdCl2{P t Bu2(p-R-Ph)}2 (R = H, NMe2, CF3,) complexes represent simple, general, and efficient catalysts for the Suzuki−Miyaura cross-coupling reactions of aryl halides including five-membered heteroaryl halides and heteroatom-substituted six-membered heteroaryl chlorides with a diver...

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Veröffentlicht in:	Organic letters 2006-04, Vol.8 (9), p.1787-1789
Hauptverfasser:	Guram, Anil S, King, Anthony O, Allen, John G, Wang, Xianghong, Schenkel, Laurie B, Chan, Johann, Bunel, Emilio E, Faul, Margaret M, Larsen, Robert D, Martinelli, Michael J, Reider, Paul J
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container_end_page	1789
container_issue	9
container_start_page	1787
container_title	Organic letters
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creator	Guram, Anil S King, Anthony O Allen, John G Wang, Xianghong Schenkel, Laurie B Chan, Johann Bunel, Emilio E Faul, Margaret M Larsen, Robert D Martinelli, Michael J Reider, Paul J
description	New air-stable PdCl2{P t Bu2(p-R-Ph)}2 (R = H, NMe2, CF3,) complexes represent simple, general, and efficient catalysts for the Suzuki−Miyaura cross-coupling reactions of aryl halides including five-membered heteroaryl halides and heteroatom-substituted six-membered heteroaryl chlorides with a diverse range of arylboronic acids. High product yields (89−99% isolated yields) and turn-over-numbers (10 000 TON) are observed.
doi_str_mv	10.1021/ol060268g
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title	New Air-Stable Catalysts for General and Efficient Suzuki−Miyaura Cross-Coupling Reactions of Heteroaryl Chlorides
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