On the spontaneous induction of chirality in the preparation of Werner's complex cis-[CoBr(NH3)(en)2]Br2

On the spontaneous induction of chirality in the preparation of Werner's complex cis-[CoBr(NH3)(en)2]Br2

The product obtained directly from the standard reaction to produce Werner's complex cis-[CoBr(NH3)(en)2]Br2 is shown, via structure determination from powder X-ray diffraction data, to be a racemic crystalline phase; implications of this observation in relation to previous reports that this re...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006-05 (17), p.1854-1856
Hauptverfasser: Guo, Fang, Casadesus, Meritxell, Cheung, Eugene Y, Coogan, Michael P, Harris, Kenneth D M
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container_issue 17
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container_title Chemical communications (Cambridge, England)
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creator Guo, Fang
Casadesus, Meritxell
Cheung, Eugene Y
Coogan, Michael P
Harris, Kenneth D M
description The product obtained directly from the standard reaction to produce Werner's complex cis-[CoBr(NH3)(en)2]Br2 is shown, via structure determination from powder X-ray diffraction data, to be a racemic crystalline phase; implications of this observation in relation to previous reports that this reaction leads to significant enantiomeric excesses are discussed.
doi_str_mv 10.1039/b601530a
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source Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
title On the spontaneous induction of chirality in the preparation of Werner's complex cis-[CoBr(NH3)(en)2]Br2
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