On the spontaneous induction of chirality in the preparation of Werner's complex cis-[CoBr(NH3)(en)2]Br2

On the spontaneous induction of chirality in the preparation of Werner's complex cis-[CoBr(NH3)(en)2]Br2

The product obtained directly from the standard reaction to produce Werner's complex cis-[CoBr(NH3)(en)2]Br2 is shown, via structure determination from powder X-ray diffraction data, to be a racemic crystalline phase; implications of this observation in relation to previous reports that this re...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006-05 (17), p.1854-1856
Hauptverfasser: Guo, Fang, Casadesus, Meritxell, Cheung, Eugene Y, Coogan, Michael P, Harris, Kenneth D M
Format: Artikel
Sprache:eng
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Zusammenfassung:The product obtained directly from the standard reaction to produce Werner's complex cis-[CoBr(NH3)(en)2]Br2 is shown, via structure determination from powder X-ray diffraction data, to be a racemic crystalline phase; implications of this observation in relation to previous reports that this reaction leads to significant enantiomeric excesses are discussed.
ISSN:1359-7345
1364-548X
DOI:10.1039/b601530a