High-Resolution NMR Spectroscopy with a Portable Single-Sided Sensor

We report construction of a portable nuclear magnetic resonance sensor with a single-sided open probe design. The resulting magnetic field inhomogeneity is compensated by a pulse sequence that takes advantage of parallel inhomogeneity in the applied radio frequency field. We can thereby acquire fluo...

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Veröffentlicht in:Science (American Association for the Advancement of Science) 2005-05, Vol.308 (5726), p.1279-1279
Hauptverfasser: Perlo, Juan, Demas, Vasiliki, Casanova, Federico, Meriles, Carlos A, Reimer, Jeffrey, Pines, Alexander, Blůmich, Bernhard
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container_issue 5726
container_start_page 1279
container_title Science (American Association for the Advancement of Science)
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creator Perlo, Juan
Demas, Vasiliki
Casanova, Federico
Meriles, Carlos A
Reimer, Jeffrey
Pines, Alexander
Blůmich, Bernhard
description We report construction of a portable nuclear magnetic resonance sensor with a single-sided open probe design. The resulting magnetic field inhomogeneity is compensated by a pulse sequence that takes advantage of parallel inhomogeneity in the applied radio frequency field. We can thereby acquire fluorine-19 spectra of liquid fluorocarbons with 8 parts per million resolution, surmounting the long-standing obstacle of obtaining chemical shift information with open probe instruments.
doi_str_mv 10.1126/science.1108944
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source American Association for the Advancement of Science; Jstor Complete Legacy
subjects Brevia
Chemical equilibrium
Chemistry
Departments
Design and construction
Exact sciences and technology
Fluorescence
High resolution spectroscopy
Infrared, submillimeter wave, microwave and radiowave instruments, equipment and techniques
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
Instruments, apparatus, components and techniques common to several branches of physics and astronomy
Magnetic fields
Magnetic spectroscopy
Magnets
Materials
NMR
NMR SPECTROMETERS
NUCLEAR MAGNETIC RESONANCE
Nuclear magnetic resonance spectroscopy
Organic Chemistry
OTHER INSTRUMENTATION
Physics
PORTABLE EQUIPMENT
RESOLUTION
Scientific equipment
Scientific equipment and supplies
Sensors
Spectroscopy
Submillimeter wave, microwave and radiowave spectrometers
magnetic resonance spectrometers, auxiliary equipment, and techniques
Submillimeter wave, microwave and radiowave spectrometers
magnetic resonance spectrometers, auxiliary equipments and techniques
title High-Resolution NMR Spectroscopy with a Portable Single-Sided Sensor
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