High-Resolution NMR Spectroscopy with a Portable Single-Sided Sensor
We report construction of a portable nuclear magnetic resonance sensor with a single-sided open probe design. The resulting magnetic field inhomogeneity is compensated by a pulse sequence that takes advantage of parallel inhomogeneity in the applied radio frequency field. We can thereby acquire fluo...
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Veröffentlicht in: | Science (American Association for the Advancement of Science) 2005-05, Vol.308 (5726), p.1279-1279 |
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creator | Perlo, Juan Demas, Vasiliki Casanova, Federico Meriles, Carlos A Reimer, Jeffrey Pines, Alexander Blůmich, Bernhard |
description | We report construction of a portable nuclear magnetic resonance sensor with a single-sided open probe design. The resulting magnetic field inhomogeneity is compensated by a pulse sequence that takes advantage of parallel inhomogeneity in the applied radio frequency field. We can thereby acquire fluorine-19 spectra of liquid fluorocarbons with 8 parts per million resolution, surmounting the long-standing obstacle of obtaining chemical shift information with open probe instruments. |
doi_str_mv | 10.1126/science.1108944 |
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subjects | Brevia Chemical equilibrium Chemistry Departments Design and construction Exact sciences and technology Fluorescence High resolution spectroscopy Infrared, submillimeter wave, microwave and radiowave instruments, equipment and techniques INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Instruments, apparatus, components and techniques common to several branches of physics and astronomy Magnetic fields Magnetic spectroscopy Magnets Materials NMR NMR SPECTROMETERS NUCLEAR MAGNETIC RESONANCE Nuclear magnetic resonance spectroscopy Organic Chemistry OTHER INSTRUMENTATION Physics PORTABLE EQUIPMENT RESOLUTION Scientific equipment Scientific equipment and supplies Sensors Spectroscopy Submillimeter wave, microwave and radiowave spectrometers magnetic resonance spectrometers, auxiliary equipment, and techniques Submillimeter wave, microwave and radiowave spectrometers magnetic resonance spectrometers, auxiliary equipments and techniques |
title | High-Resolution NMR Spectroscopy with a Portable Single-Sided Sensor |
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