Formation of aluminacyclobutenes via carbon monoxide and isocyanide insertion

Formation of aluminacyclobutenes via carbon monoxide and isocyanide insertion

Reaction of LAl[eta2-(CSiMe3)2] (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) with carbon monoxide and tert-butyl isocyanide afforded unique AlC3 aluminacyclobutenes via insertion into one of the aluminium-carbon bonds.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006-01 (16), p.1763-1765
Hauptverfasser: Li, Xiaofei, Ni, Chengbao, Song, Haibing, Cui, Chunming
Format: Artikel
Sprache:eng
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Zusammenfassung:Reaction of LAl[eta2-(CSiMe3)2] (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) with carbon monoxide and tert-butyl isocyanide afforded unique AlC3 aluminacyclobutenes via insertion into one of the aluminium-carbon bonds.
ISSN:1359-7345
1364-548X
DOI:10.1039/b601056c