Cycloaddition between Electron-Deficient π-Systems, Photochemical and Radical-Induced Reactions:  A Novel, General, and Stereoselective Route to Polyfunctionalized Bridged Bicyclo[2.2.2]octanes, Bicyclo[3.3.0]octanes, Bicyclo[4.2.0]octanes, and Tricyclo[4.3.1.03,7]decanes

A novel, general, and stereoselective route to functionalized bridged bicyclo[2.2.2]octanes, bicyclo[3.3.0]octanes, bicyclo[4.2.0]octanes, and tricyclo[4.3.1.03,7]decanes has been described. Various functionalized and sustituted bicyclo[2.2.2]octanes endowed with a β,γ-enone chromophore were synthes...

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Veröffentlicht in:Journal of organic chemistry 2006-04, Vol.71 (8), p.3014-3025
Hauptverfasser: Singh, Vishwakarma, Pal, Shantanu, Mobin, Shaikh M
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Sprache:eng
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