Benzonitrile Extrusion from Molybdenum(IV) Ketimide Complexes Obtained via Radical C−E (E = O, S, Se) Bond Formation:  Toward a New Nitrogen Atom Transfer Reaction

Beta-elimination is explored as a possible means of nitrogen-atom transfer into organic molecules. Molybdenum(IV) ketimide complexes of formula (Ar[t-Bu]N)3Mo(NC(X)Ph), where Ar = 3,5-Me2C6H3 and X = SC6F5, SeC6F5, or O2CPh, are formally derived from addition of the carbene fragment [:C(X)Ph] to th...

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Veröffentlicht in:	Journal of the American Chemical Society 2006-04, Vol.128 (14), p.4881-4891
Hauptverfasser:	Mendiratta, Arjun, Cummins, Christopher C, Kryatova, Olga P, Rybak-Akimova, Elena V, McDonough, James E, Hoff, Carl D
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Inorganic chemistry and origins of life Kinetics and mechanism of reactions
Online-Zugang:	Volltext
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