Detoxification pathways of the phytoalexins brassilexin and sinalexin in Leptosphaeria maculans: isolation and synthesis of the elusive intermediate 3-formylindolyl-2-sulfonic acid

Brassilexin and sinalexin are among the most potent antifungal phytoalexins produced by crucifer plants. Nonetheless, the crucifer pathogen Leptosphaeria maculans(Desm.) Ces. et de Not. (asexual stage Phoma lingam(Tode ex Fr.) Desm.) is able to detoxify these phytoalexins. To understand and control...

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Veröffentlicht in:	Organic & biomolecular chemistry 2005-05, Vol.3 (10), p.2002-2007
Hauptverfasser:	Pedras, M Soledade C, Suchy, Mojmir
Format:	Artikel
Sprache:	eng
Schlagworte:	Ascomycota - metabolism Chromatography, High Pressure Liquid Indoles - chemical synthesis Indoles - isolation & purification Indoles - metabolism Magnetic Resonance Spectroscopy Spectrometry, Mass, Electrospray Ionization Sulfonic Acids - chemical synthesis Sulfonic Acids - isolation & purification Thiazoles - metabolism
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