Asymmetric Claisen Rearrangements Enabled by Catalytic Asymmetric Di(allyl) Ether Synthesis

Merging the catalytic asymmetric synthesis of di(allyl) ethers with ensuing olefin isomerization-Claisen rearrangement (ICR) reactions provides a convenient, two-step route to asymmetric aliphatic Claisen rearrangements from easily obtained starting materials. These reactions deliver the 2,3-disubst...

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Veröffentlicht in:	Journal of the American Chemical Society 2006-04, Vol.128 (13), p.4232-4233
Hauptverfasser:	Nelson, Scott G, Wang, Kan
Format:	Artikel
Sprache:	eng
Schlagworte:	Allyl Compounds - chemical synthesis Catalysis Chemistry Ethers - chemical synthesis Exact sciences and technology Organic chemistry Organometallic Compounds - chemistry Propanols - chemistry Zinc - chemistry
Online-Zugang:	Volltext
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