Titanium(IV) Citrate Speciation and Structure under Environmentally and Biologically Relevant Conditions

The water-soluble complexes of Ti(IV) with citrate are of interest in environmental, biological, and materials chemistry. The aqueous solution speciation is revealed by spectropotentiometric titration. From pH 3−8, given at least three equivalents of ligand, 3:1 citrate/titanium complexes predominat...

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Veröffentlicht in:	Inorganic chemistry 2005-05, Vol.44 (10), p.3431-3440
Hauptverfasser:	Collins, Joseph M, Uppal, Ritika, Incarvito, Christopher D, Valentine, Ann M
Format:	Artikel
Sprache:	eng
Schlagworte:	Citrates - chemistry Crystallography, X-Ray Hydrogen-Ion Concentration Magnetic Resonance Spectroscopy Models, Chemical Molecular Conformation Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Titanium - chemistry Water - chemistry
Online-Zugang:	Volltext
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