Strong Means Slow: Dynamic Contributions to the Bulk Mechanical Properties of Supramolecular Networks

Hold on tight: The dynamics, rather than thermodynamics, of reversible cross‐links are the primary determinants of bulk viscosities in a family of supramolecular networks. This result comes from a study in which a series of structurally similar pincer complexes (see picture, OTf=CF3SO3−) that have d...

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Veröffentlicht in:	Angewandte Chemie International Edition 2005-04, Vol.44 (18), p.2746-2748
Hauptverfasser:	Yount, Wayne C., Loveless, David M., Craig, Stephen L.
Format:	Artikel
Sprache:	eng
Schlagworte:	Cross-Linking Reagents - chemistry gels Kinetics mechanical properties Models, Chemical Molecular Structure pincer complexes polymers Polyvinyls - chemistry Pyridines - chemistry Software supramolecular chemistry Thermodynamics
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description	Hold on tight: The dynamics, rather than thermodynamics, of reversible cross‐links are the primary determinants of bulk viscosities in a family of supramolecular networks. This result comes from a study in which a series of structurally similar pincer complexes (see picture, OTf=CF3SO3−) that have different ligand‐exchange dynamics is used to cross‐link poly(4‐vinylpyridine).
doi_str_mv	10.1002/anie.200500026
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subjects	Cross-Linking Reagents - chemistry gels Kinetics mechanical properties Models, Chemical Molecular Structure pincer complexes polymers Polyvinyls - chemistry Pyridines - chemistry Software supramolecular chemistry Thermodynamics
title	Strong Means Slow: Dynamic Contributions to the Bulk Mechanical Properties of Supramolecular Networks
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