Chasing a Phantom by Total Synthesis: The Butylcycloheptylprodigiosin Case

The dispute as to whether “butylcycloheptylprodigiosin” is a natural product or solely a misassigned structure lasted for more than a decade. This open question has now been answered by the first total synthesis of this tripyrrole alkaloid (see picture), which makes explicit use of the peculiarities...

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Veröffentlicht in:	Angewandte Chemie International Edition 2005-04, Vol.44 (18), p.2777-2781
Hauptverfasser:	Fürstner, Alois, Radkowski, Karin, Peters, Hartwig
Format:	Artikel
Sprache:	eng
Schlagworte:	alkaloids cyclophanes Esters - chemistry medium-ring compounds Molecular Structure palladium Phantoms, Imaging Prodigiosin - analogs & derivatives Prodigiosin - chemical synthesis Prodigiosin - chemistry pyrroles Pyrroles - chemistry
Online-Zugang:	Volltext
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