Attachment of organic layers to conductive or semiconductive surfaces by reduction of diazonium salts
Surface chemistry is the topic of this tutorial review. It describes the electrochemical reduction of aryl diazonium salts on carbon, silicon or metals which leads to the formation of an aromatic organic layer covalently bonded to the surface. The method which permits such a modification is set fort...
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| Veröffentlicht in: | Chemical Society reviews 2005-01, Vol.34 (5), p.429-439 |
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| container_title | Chemical Society reviews |
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| creator | Pinson, Jean Podvorica, Fetah |
| description | Surface chemistry is the topic of this tutorial review. It describes the electrochemical reduction of aryl diazonium salts on carbon, silicon or metals which leads to the formation of an aromatic organic layer covalently bonded to the surface. The method which permits such a modification is set forth. The proof for the existence of the organic layer is brought forward. The grafting mechanism and the covalent bonding between the surface and the aryl group are discussed. The formation of mono or multilayers depending on the experimental conditions is rationalized. Finally some examples of the possible uses of this reaction are given. |
| doi_str_mv | 10.1039/b406228k |
| format | Article |
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It describes the electrochemical reduction of aryl diazonium salts on carbon, silicon or metals which leads to the formation of an aromatic organic layer covalently bonded to the surface. The method which permits such a modification is set forth. The proof for the existence of the organic layer is brought forward. The grafting mechanism and the covalent bonding between the surface and the aryl group are discussed. The formation of mono or multilayers depending on the experimental conditions is rationalized. 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| ispartof | Chemical Society reviews, 2005-01, Vol.34 (5), p.429-439 |
| issn | 0306-0012 1460-4744 |
| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals; Royal Society of Chemistry Journals Archive (1841-2007); Alma/SFX Local Collection |
| subjects | Diazonium Compounds - chemical synthesis Diazonium Compounds - chemistry Electric Conductivity Electrochemistry Materials Testing Membranes, Artificial Organic Chemicals - chemistry Oxidation-Reduction Semiconductors Surface Properties |
| title | Attachment of organic layers to conductive or semiconductive surfaces by reduction of diazonium salts |
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