Iron nanoparticles in the coupling of alkyl halides with aryl Grignard reagents

Iron nanoparticles in the coupling of alkyl halides with aryl Grignard reagents

Iron nanoparticles, either formed in situ stabilized by 1,6-bis(diphenylphosphino)hexane or polyethylene glycol (PEG), or preformed stabilized by PEG, are excellent catalysts for the cross-coupling of aryl Grignard reagents with primary and secondary alkyl halides bearing beta-hydrogens and they als...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2006-01 (13), p.1398-1400
Hauptverfasser: Bedford, Robin B, Betham, Michael, Bruce, Duncan W, Davis, Sean A, Frost, Robert M, Hird, Michael
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container_issue 13
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container_title Chemical communications (Cambridge, England)
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creator Bedford, Robin B
Betham, Michael
Bruce, Duncan W
Davis, Sean A
Frost, Robert M
Hird, Michael
description Iron nanoparticles, either formed in situ stabilized by 1,6-bis(diphenylphosphino)hexane or polyethylene glycol (PEG), or preformed stabilized by PEG, are excellent catalysts for the cross-coupling of aryl Grignard reagents with primary and secondary alkyl halides bearing beta-hydrogens and they also prove effective in a tandem cyclization/cross-coupling reaction.
doi_str_mv 10.1039/b601014h
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title Iron nanoparticles in the coupling of alkyl halides with aryl Grignard reagents
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