Stabilization of Charge-Separated States in Phthalocyanine−Fullerene Ensembles through Supramolecular Donor−Acceptor Interactions

A novel ZnPc−C60 dyad (3), in which two photoactive units are brought together by a phenylenevinylene spacer has been synthesized. The synthetic strategy en route toward 3 involves a Heck reaction to attach 4-vinylbenzaldehyde to a monoiodophthalocyanine precursor, followed by standard cycloaddition...

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Veröffentlicht in:	Journal of the American Chemical Society 2006-03, Vol.128 (12), p.4112-4118
Hauptverfasser:	de la Escosura, Andrés, Martínez-Díaz, M. Victoria, Guldi, Dirk M, Torres, Tomás
Format:	Artikel
Sprache:	eng
Schlagworte:	Biomimetic Materials - chemistry Carboxylic Acids - chemistry Fullerenes - chemistry Indoles - chemistry Organometallic Compounds - chemistry Spectrometry, Fluorescence Spectrophotometry, Ultraviolet Zinc - chemistry
Online-Zugang:	Volltext
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