Borylene Transfer under Thermal Conditions: Synthesis and Structure of a Tetrarhodium Bisborylene Complex

All good things come in fours: Thermal metal–metal borylene transfer from the terminal borylene complexes [(OC)5MBN(SiMe3)2] (M=Cr, W) leads to the new tetranuclear rhodium complex [Rh4{μ‐BN(SiMe3)2}2(μ‐Cl)4(μ‐CO)(CO)4] (see structure), which is the first doubly borylene‐bridged transition‐metal co...

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Veröffentlicht in:	Angewandte Chemie International Edition 2006-03, Vol.45 (13), p.2132-2134
Hauptverfasser:	Braunschweig, Holger, Forster, Melanie, Radacki, Krzysztof
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Sprache:	eng
Schlagworte:	boron borylene complexes bridging ligands rhodium
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creator	Braunschweig, Holger Forster, Melanie Radacki, Krzysztof
description	All good things come in fours: Thermal metal–metal borylene transfer from the terminal borylene complexes [(OC)5MBN(SiMe3)2] (M=Cr, W) leads to the new tetranuclear rhodium complex [Rh4{μ‐BN(SiMe3)2}2(μ‐Cl)4(μ‐CO)(CO)4] (see structure), which is the first doubly borylene‐bridged transition‐metal complex. In the solid state, the tetranuclear units aggregate (dashed lines), giving a rare example of a neutral chain of rhodium atoms.
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title	Borylene Transfer under Thermal Conditions: Synthesis and Structure of a Tetrarhodium Bisborylene Complex
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