AFM Observation of Immobilized Self-Oscillating Polymer

Various types of nanocomponents have been developed to construct a nanodevice or nanomachine. Here, we add a new nanocomponent that has the function of self-oscillation. A thermoresponsive polymer carrying a Ru complex, a catalyst of the Belousov−Zhabotinsky reaction, was synthesized and immobilized...

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Veröffentlicht in:The journal of physical chemistry. B 2006-03, Vol.110 (11), p.5170-5173
Hauptverfasser: Ito, Yoshihiro, Hara, Yusuke, Uetsuka, Hiroshi, Hasuda, Hirokazu, Onishi, Hiroshi, Arakawa, Hideo, Ikai, Atsushi, Yoshida, Ryo
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container_end_page 5173
container_issue 11
container_start_page 5170
container_title The journal of physical chemistry. B
container_volume 110
creator Ito, Yoshihiro
Hara, Yusuke
Uetsuka, Hiroshi
Hasuda, Hirokazu
Onishi, Hiroshi
Arakawa, Hideo
Ikai, Atsushi
Yoshida, Ryo
description Various types of nanocomponents have been developed to construct a nanodevice or nanomachine. Here, we add a new nanocomponent that has the function of self-oscillation. A thermoresponsive polymer carrying a Ru complex, a catalyst of the Belousov−Zhabotinsky reaction, was synthesized and immobilized on a glass plate. Periodic turbidity changes in the aqueous solution of the polymer were observed, and nanoscale self-oscillation of the immobilized polymer was observed by a scanning probe microscope.
doi_str_mv 10.1021/jp060284v
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subjects Catalysis
Glass - chemistry
Microscopy, Atomic Force - methods
Organometallic Compounds - chemical synthesis
Polymers - chemistry
Ruthenium - chemistry
Solutions - chemistry
Surface Properties
Time Factors
Water - chemistry
title AFM Observation of Immobilized Self-Oscillating Polymer
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