Molecular Tectonics. Selective Exchange of Cations in Porous Anionic Hydrogen-Bonded Networks Built from Derivatives of Tetraphenylborate
Tetraphenylmethanes with multiple hydrogen-bonding sites are known to associate to form robust porous supramolecular networks. Analogous anionic networks can be built from the corresponding tetraphenylborates. Crystallization of the tetraphenylphosphonium salt of tetraphenylborate 2 produces an anio...
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| Veröffentlicht in: | Journal of the American Chemical Society 2005-04, Vol.127 (16), p.5910-5916 |
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| creator | Malek, Nadia Maris, Thierry Simard, Michel Wuest, James D |
| description | Tetraphenylmethanes with multiple hydrogen-bonding sites are known to associate to form robust porous supramolecular networks. Analogous anionic networks can be built from the corresponding tetraphenylborates. Crystallization of the tetraphenylphosphonium salt of tetraphenylborate 2 produces an anionic network in which 74% of the volume is available for including cations and neutral guests. Other salts of anion 2 with diverse cations crystallize consistently to form the same network, whereas a neutral analogue of anion 2, tetraphenylmethane 1, produces an uncharged network that is far less open. Cations can be exchanged in single crystals of salts of tetraphenylborate 2 with retention of crystallinity and with selectivities similar to those observed in typical zeolites. Together, these observations provide new strategies for making ordered molecular materials by design, and they reveal that constructing such materials from charged subunits offers special advantages. |
| doi_str_mv | 10.1021/ja042233m |
| format | Article |
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Selective Exchange of Cations in Porous Anionic Hydrogen-Bonded Networks Built from Derivatives of Tetraphenylborate</title><source>ACS Publications</source><creator>Malek, Nadia ; Maris, Thierry ; Simard, Michel ; Wuest, James D</creator><creatorcontrib>Malek, Nadia ; Maris, Thierry ; Simard, Michel ; Wuest, James D</creatorcontrib><description>Tetraphenylmethanes with multiple hydrogen-bonding sites are known to associate to form robust porous supramolecular networks. Analogous anionic networks can be built from the corresponding tetraphenylborates. Crystallization of the tetraphenylphosphonium salt of tetraphenylborate 2 produces an anionic network in which 74% of the volume is available for including cations and neutral guests. Other salts of anion 2 with diverse cations crystallize consistently to form the same network, whereas a neutral analogue of anion 2, tetraphenylmethane 1, produces an uncharged network that is far less open. Cations can be exchanged in single crystals of salts of tetraphenylborate 2 with retention of crystallinity and with selectivities similar to those observed in typical zeolites. Together, these observations provide new strategies for making ordered molecular materials by design, and they reveal that constructing such materials from charged subunits offers special advantages.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja042233m</identifier><identifier>PMID: 15839690</identifier><identifier>CODEN: JACSAT</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Condensed matter: structure, mechanical and thermal properties ; Crystal binding; cohesive energy ; Crystalline state (including molecular motions in solids) ; Exact sciences and technology ; Physics ; Structure of solids and liquids; crystallography</subject><ispartof>Journal of the American Chemical Society, 2005-04, Vol.127 (16), p.5910-5916</ispartof><rights>Copyright © 2005 American Chemical Society</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a447t-2c89018b365a9fcbd88c5291c5025aa592105172359228cd429946004def78df3</citedby><cites>FETCH-LOGICAL-a447t-2c89018b365a9fcbd88c5291c5025aa592105172359228cd429946004def78df3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ja042233m$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ja042233m$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2751,27055,27903,27904,56716,56766</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16723955$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/15839690$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Malek, Nadia</creatorcontrib><creatorcontrib>Maris, Thierry</creatorcontrib><creatorcontrib>Simard, Michel</creatorcontrib><creatorcontrib>Wuest, James D</creatorcontrib><title>Molecular Tectonics. Selective Exchange of Cations in Porous Anionic Hydrogen-Bonded Networks Built from Derivatives of Tetraphenylborate</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>Tetraphenylmethanes with multiple hydrogen-bonding sites are known to associate to form robust porous supramolecular networks. Analogous anionic networks can be built from the corresponding tetraphenylborates. Crystallization of the tetraphenylphosphonium salt of tetraphenylborate 2 produces an anionic network in which 74% of the volume is available for including cations and neutral guests. Other salts of anion 2 with diverse cations crystallize consistently to form the same network, whereas a neutral analogue of anion 2, tetraphenylmethane 1, produces an uncharged network that is far less open. Cations can be exchanged in single crystals of salts of tetraphenylborate 2 with retention of crystallinity and with selectivities similar to those observed in typical zeolites. Together, these observations provide new strategies for making ordered molecular materials by design, and they reveal that constructing such materials from charged subunits offers special advantages.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Crystal binding; cohesive energy</subject><subject>Crystalline state (including molecular motions in solids)</subject><subject>Exact sciences and technology</subject><subject>Physics</subject><subject>Structure of solids and liquids; crystallography</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNptkMtuEzEUhi0EoqGw4AWQN1RiMcX2jOeybENLkApESgCJjXXiOdM6nbGD7SnNI_DWOErUsmDl2-dP__kJec3ZKWeCv18DK4TI8-EJmXApWCa5KJ-SCWNMZFVd5kfkRQjrdCxEzZ-TIy7rvCkbNiF_Prse9diDp0vU0VmjwyldYLqM5g7pxb2-AXuN1HV0CtE4G6ixdO68GwM9s2b3g862rXfXaLNzZ1ts6ReMv52_DfR8NH2knXcD_YDe3MFOGnayJUYPmxu0237lPER8SZ510Ad8dViPybfLi-V0ll19_fhpenaVQVFUMRO6bhivV3kpoen0qq1rLUXDtWRCAshGcCZ5JfK0E7VuC9E0RZkmb7Gr6rbLj8nJ3rvx7teIIarBBI19DxbTTKqsKlnKqkjguz2ovQvBY6c23gzgt4oztetdPfSe2DcH6bgasH0kD0Un4O0BgKCh7zxYbcIjV6bEjZSJy_acCRHvH97B36ZgeSXVcr5Qi8v5j58z_l394wUd1NqN3qbu_hPwL4ICprI</recordid><startdate>20050427</startdate><enddate>20050427</enddate><creator>Malek, Nadia</creator><creator>Maris, Thierry</creator><creator>Simard, Michel</creator><creator>Wuest, James D</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20050427</creationdate><title>Molecular Tectonics. Selective Exchange of Cations in Porous Anionic Hydrogen-Bonded Networks Built from Derivatives of Tetraphenylborate</title><author>Malek, Nadia ; Maris, Thierry ; Simard, Michel ; Wuest, James D</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a447t-2c89018b365a9fcbd88c5291c5025aa592105172359228cd429946004def78df3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Crystal binding; cohesive energy</topic><topic>Crystalline state (including molecular motions in solids)</topic><topic>Exact sciences and technology</topic><topic>Physics</topic><topic>Structure of solids and liquids; crystallography</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Malek, Nadia</creatorcontrib><creatorcontrib>Maris, Thierry</creatorcontrib><creatorcontrib>Simard, Michel</creatorcontrib><creatorcontrib>Wuest, James D</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Malek, Nadia</au><au>Maris, Thierry</au><au>Simard, Michel</au><au>Wuest, James D</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Molecular Tectonics. Selective Exchange of Cations in Porous Anionic Hydrogen-Bonded Networks Built from Derivatives of Tetraphenylborate</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2005-04-27</date><risdate>2005</risdate><volume>127</volume><issue>16</issue><spage>5910</spage><epage>5916</epage><pages>5910-5916</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>Tetraphenylmethanes with multiple hydrogen-bonding sites are known to associate to form robust porous supramolecular networks. Analogous anionic networks can be built from the corresponding tetraphenylborates. Crystallization of the tetraphenylphosphonium salt of tetraphenylborate 2 produces an anionic network in which 74% of the volume is available for including cations and neutral guests. Other salts of anion 2 with diverse cations crystallize consistently to form the same network, whereas a neutral analogue of anion 2, tetraphenylmethane 1, produces an uncharged network that is far less open. Cations can be exchanged in single crystals of salts of tetraphenylborate 2 with retention of crystallinity and with selectivities similar to those observed in typical zeolites. Together, these observations provide new strategies for making ordered molecular materials by design, and they reveal that constructing such materials from charged subunits offers special advantages.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>15839690</pmid><doi>10.1021/ja042233m</doi><tpages>7</tpages></addata></record> |
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| subjects | Condensed matter: structure, mechanical and thermal properties Crystal binding cohesive energy Crystalline state (including molecular motions in solids) Exact sciences and technology Physics Structure of solids and liquids crystallography |
| title | Molecular Tectonics. Selective Exchange of Cations in Porous Anionic Hydrogen-Bonded Networks Built from Derivatives of Tetraphenylborate |
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